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Volumn 53, Issue 45, 1997, Pages 15321-15329

Observation and analysis of a slow termination process in the atom transfer radical polymerization of styrene

Author keywords

[No Author keywords available]

Indexed keywords

RADICAL; STYRENE;

EID: 0030662031     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(97)00965-4     Document Type: Article
Times cited : (128)

References (37)
  • 2
    • 0343831627 scopus 로고    scopus 로고
    • U.S. Patent 4,581,429 (1986)
    • Nitroxyl radical-mediated polymerizations: (a) Solomon, D. H.; Rizzardo, P.; Cacioli, U.S. Patent 4,581,429 (1986).
    • Solomon, D.H.1    Rizzardo, P.2    Cacioli3
  • 26
    • 0342960582 scopus 로고    scopus 로고
    • note
    • Ligand syntheses, the purification of reagents, and experimental procedures for conducting polymerizations and kinetics were reported previously. See reference 8.
  • 27
    • 0343831617 scopus 로고    scopus 로고
    • note
    • 1H NMR spectra were recorded using a 300 MHz Broker NMR spectrometer.
  • 28
    • 0342526332 scopus 로고
    • -, a gauge of the ionization of 1-PEC1 in various solvents: Diaz, A.; Winstein, S. J. Am. Chem. Soc. 1964, 86, 5010.
    • (1964) J. Am. Chem. Soc. , vol.86 , pp. 5010
    • Diaz, A.1    Winstein, S.2
  • 29
    • 0000684712 scopus 로고
    • Wilkinson, G., Gillard, R. D. and McCleverty, J. A., Eds.; Pergamon: Oxford
    • (a) Hathaway, B. J. in Comprehensive Inorganic Chemistry; Wilkinson, G., Gillard, R. D. and McCleverty, J. A., Eds.; Pergamon: Oxford, 1987; Vol. 5, pp 533-593.
    • (1987) Comprehensive Inorganic Chemistry , vol.5 , pp. 533-593
    • Hathaway, B.J.1
  • 32
    • 0343831616 scopus 로고    scopus 로고
    • note
    • 2 was not used, because it would have resulted in reverse ATRP and made the experiment inconclusive (see reference 8). The use of the triflate anion ensured that free-radical polymerization would occur without molecular weight control via transfer of the counteranion.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.