Direct ethoxylation of fatty methyl ester over Al-Mg composite oxide catalyst

JAOCS, Journal of the American Oil Chemists' Society

Volumn 74, Issue 1, 1997, Pages 19-24

  Hama, I ^a   Okamoto, T ^a   Hidai, E ^a   Yamada, K ^a  

^a LION CORPORATION   (Japan)

Author keywords

Al Mg composite oxide catalyst; Coordination anionic polymerization; Direct ethoxylation; Ethoxylated fatty methyl ester; Ethoxylation; Ethylene oxide; Fatty methyl ester; Nonionic surfactant; Reaction mechanism; Solid catalyst

Indexed keywords

ALUMINA; ANIONIC POLYMERIZATION; CATALYSTS; CHEMICAL BONDS; CHEMISORPTION; COMPOSITION EFFECTS; MAGNESIA; OXYGEN; POLYETHYLENE OXIDES; REACTION KINETICS; SURFACE ACTIVE AGENTS; SYNTHESIS (CHEMICAL);

ETHOXYLATION; FATTY METHYL ESTERS; NONIONIC SURFACTANTS;

ESTERS;

EID: 0030646342     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-997-0113-1     Document Type: Article

References (8)

1. Hama, I., T. Okamoto, and H. Nakamura, Preparation and Properties of Ethoxylated Fatty Methyl Ester Nonionics, J. Am. Oil Chem. Soc. 72:781-784 (1995).
2. Schick, M.J., Nonionic Surfactants, Marcel Dekker, New York, 1966, pp. 8-43.
3. Bender, M.L., and R.J. Thomas, The Concurrent Alkaline Hydrolysis and Isotopic Oxygen Exchange of a Series of p-Substituted Methyl Benzoates, J. Am. Chem. Soc. 83:4193-4196 (1961).
4. Shain, S.A., and J.F. Kirsch, Absence of Carbonyl Oxygen Exchange Concurrent with the Alkaline Hydrolysis of Substituted Methyl Benzoates, Ibid. 90:5848-5854 (1968).
5. McClelland, R.A., Rate-Limiting Deprotonation in Tetrahedral Intermediate Breakdown, Ibid. 106:7579-7583 (1984).
6. Wiberg, K.B., The Thermal Rearrangement of Methyl Benzoate, Ibid. 75:2665-2666 (1953).
7. Bender, M.L., Oxygen Exchange as Evidence for the Existence of an Intermediate in Ester Hydrolysis, Ibid. 73:1626-1629 (1951).
8. Hama, I., T. Okamoto, H. Sasamoto, and H. Nakamura, Japanese Patent JP6-277016A (1994).