Estimation of the time to maximum rate using dynamic DSC experiments

Journal of Loss Prevention in the Process Industries

Volumn 10, Issue 1, 1997, Pages 31-41

  Keller, Andreas ^a   Stark, Daniel ^a   Fierz, Hans ^b   Heinzle, Elmar ^a   Hungerbühler, Konrad ^a  

^a ETH ZURICH   (Switzerland)

^b CIBA GEIGY LTD   (Switzerland)

Author keywords

autocatalytic reaction; DSC; safety screening; simulation; thermal safety; time to maximum rate

Indexed keywords

AUTOCATALYTIC REACTION; SAFETY SCREENING; THERMAL SAFETY; TIME TO MAXIMUM RATE;

CHEMICAL REACTIONS; COMPUTER SIMULATION; DIFFERENTIAL SCANNING CALORIMETRY; ESTIMATION; PROBABILITY; RISK ASSESSMENT;

ACCIDENT PREVENTION;

EID: 0030623277     PISSN: 09504230     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0950-4230(96)00037-X     Document Type: Article

References (16)

1. [1] Stoessel, F., Chemical Engineering Progress, 1993, 10, 68-75.
2. [2] Grewer, T. Thermal Hazards of Chemical Reactions. Elsevier Science, Amsterdam, 1994.
3. [3] Gygax, R. W., Chemical Engineering Progress, 1990, 2, 53-60.
4. [4] Lambert, P. G. and Amery, G., I.Chem.E. Symposium Series, 1989, 115, 85-95.
5. [5] Steinbach, J. Chemische Sicherheitstechnik. VCH, Weinheim, 1995.
6. [6] ANSI/ASTM, Standard test method for Arrhenius kinetic constants. E 698-79, 1979.
7. [7] Townsend, D. I., Ferguson, H. D. and Kohlbrand, H. T., Process Safety Progress, 1995, 1, 71-76.
8. [8] Stoessel, F., Journal of Loss Prevention in the Process Industries, 1993, 6, 79-85.
9. [9] Gygax, R. W. Personal communication, Ciba-Geigy Ltd, Basel, 1989.
10. [10] Barton, J. and Rogers, R. Chemical Reaction Hazards. Institution of Chemical Engineers, Rugby, 1993, p. 66.
11. [11] Frank-Kamenetskii, D. A. Diffusion and Heat Transfer in Chemical Kinetics, 2nd edn. Plenum Press, New York, 1969, p. 353.
12. [12] Townsend, D. I. and Tou, J. C., Thermochimica Acta, 1980, 37, 1-30.
13. [13] MathWorks Inc. MATLAB Reference Guide. Natick, 1994.
14. [14] Hemminger, W. F. and Cammenga, H. K. Methoden der Thermischen Analyse. Springer, Berlin, 1989.
15. [15] Prout, E. G. and Tompkins, F. C., Transactions of the Faraday Society, 1944, 40, 488-498.
16. [16] Cronin, J. L., Nolan, P. F. and Barton, J. A., I.Chem.E. Symposium Series, 1987, 102, 113-132.