Product analysis of the gas-phase reaction of β-caryophyllene with ozone

Atmospheric Environment

Volumn 31, Issue 2, 1997, Pages 283-285

  Calogirou, A ^a   Kotzias, D ^a   Kettrup, A ^b  

^a JOINT RESEARCH CENTRE   (Italy)

^b INSTITUTE OF EPIDEMIOLOGY   (Germany)

Author keywords

3,3 dimethyl methylene 2 (3 oxobutyl)butanebutanal; 3,3 dimethyl oxo 2 (3 oxobutyl) cyclobutanebutanal; Atmospheric oxidation; Sesquiterpenes

Indexed keywords

CARYOPHYLLENE; CYCLOBUTANE DERIVATIVE; FORMALDEHYDE; HYDROXYL RADICAL; OZONE;

ARTICLE; CHEMICAL REACTION; OXIDATION; PRIORITY JOURNAL;

AROMATIC COMPOUNDS; ATMOSPHERIC CHEMISTRY; OXIDATION; OZONE; REACTION KINETICS;

GAS PHASE REACTIONS; SESQUITERPENES;

ATMOSPHERIC COMPOSITION;

CARYOPHYLLENE; GAS PHASE REACTION; OXIDATION; SESQUITERPENE;

EID: 0030617358     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/1352-2310(96)00190-2     Document Type: Article

References (8)

1. Arey J., Winer A. M., Atkinson R., Aschmann S. M., Long W. D., Morrison L. and Olszyk D. M. (1991) Terpenes emitted from agricultural species found in California's Central valley. J. geophys. Res. 96, 9329-9336.
2. Calogirou A., Larsen B.R., Brissol C., Duane M. and Kotzias D. (1996) Decomposition of terpenes by ozone during sampling on tenax. Anal. Chem. 68, 1499-1506.
3. Grosjean D., Williams E. L., Grosjean E., Andino J. M. and Seinfeld J. H. (1993) Atmospheric oxidation of biogenic hydrocarbons. Reaction of ozone with β-pinene, D-limonene and trans-caryophyllene. Envir. Sci. Technol. 27, 2754-2758.
4. Helmig D., Klinger L. F., Greenberg J. and Zimmermann P. (1994) Emissions and identification of individual organic compounds from vegetation in three ecosystems in the U.S. 207th ACS Meeting, Am. Chem. Soc., San Diego, California, 13-18 March.
5. König G., Brunda M., Puxbaum H., Hewitt C. N., Duckham . C. and Rudolph J. (1995) Relative contribution of oxygenated hydrocarbons to the total biogenic VOC emissions of selected mid-European agricultural and natural plant species. Atmospheric Environment 29, 861-874.
6. Kotzias D. et al. (1995) The BEMA project (Biogenic Emissions in the Mediterranean Area)-in-field measuring campaign, Burriana July '95, unpublished results.
7. Shu Y. and Atkinson R. (1994) Rate constants for the gasphase reactions of O-3 with a series of terpenes and OH radical formation from the O-3 reactions with sesquiterpenes at 296 ± 2 K, Int. J. Chem. Kinet. 26, 1193-1205.
8. Shu Y. and Atkinson R. (1995) Atmospheric lifetimes and fates of a series of sesquiterpenes. J. geophys. Res. 100, 7275-7281.