Oxidation of tri- and perchloroethene in aqueous solution with ozone and hydrogen peroxide in a tube reactor

Water Research

Volumn 31, Issue 1, 1997, Pages 33-40

  Sunder, Matthias ^a   Hempel, Dietmar Christian ^b,c  

^a UNIVERSITY OF PADERBORN   (Germany)

^b TECHNICAL UNIVERSITY OF BRAUNSCHWEIG   (Germany)

^c HENKEL KGAA   (Germany)

Author keywords

Advanced oxidation process; Hydrogen peroxide; Hydroxyl radical; Ozone; PCE; TCE; Tube reactor

Indexed keywords

BICARBONATE; CHLORIDE ION; GROUND WATER; HYDROGEN PEROXIDE; OZONE; TRICHLOROETHYLENE;

ARTICLE; KINETICS; MATHEMATICAL MODEL; OXIDATION; PRIORITY JOURNAL; STOICHIOMETRY; WATER POLLUTION; WATER TREATMENT;

AQUEOUS SOLUTIONS; OXIDATION; POLLUTANTS; REACTIONS;

CHEMICAL REACTORS; CHLORINE; HYDROGEN PEROXIDE; MATHEMATICAL MODELS; OLEFINS; OXIDATION; PH EFFECTS; POTABLE WATER; REACTION KINETICS; SOLUTIONS; STOICHIOMETRY;

DIMINERALIZED WATER; PERCHLOROETHENE; TRICHLOROETHENE; TUBE REACTOR;

WATER TREATMENT;

EID: 0030617172     PISSN: 00431354     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0043-1354(96)00218-7     Document Type: Article

References (16)

1. Aieta E. M., Reagan K. M., Lang J. S., McReynolds L., Kang J. W. and Glaze W. H. (1988) Advanced oxidation processes for treating groundwater contaminated with TCE and PCE: Pilot-seals evaluations. J. AWWA 80, 64-72.
2. Behar D., Czapski G. and Duchovny I. (1970) Carbonate radical in flash photolysis and pulse radiolysis of aqueous carbonate solutions. J. Phys. Chem. 74, 2206-2210.
3. - as intermediates. J. Phys. Chem. 88, 2560-2564 and 5450 (erratum).
4. Bünning G. (1996) Continuous disinfection with ozone in tube reactors. Ph.D. Thesis, University of Paderborn, Dissertations Druck Darmstadt, ISBN 3-931713-06-7, Germany.
5. -) in aqueous solution. J. Phys. Chem. Ref. Data 17, 513-886.
6. Glaze W. and Kang J. W. (1989) Advanced oxidation processes. Test of a kinetic model for the oxidation of organic compounds with ozone and hydrogen peroxide in a semibatch reactor. Ind. Eng. Chem. Res. 28, 1580-1587.
7. Hoigné J. (1982) Mechanisms, rates and selectivities of oxidations of organic compounds initiated by ozonation of water. In Handbook of Ozone Technology and Applications (Edited by R. G. Rice and A. Netzer), pp. 341-379. Ann Arbor Science Publishers, Ann Arbor, Michigan.
8. Hoigné J. and Bader H. (1983) Rate constants of reactions of ozone with organic and inorganic compounds in water - I: Non-dissociating organic compounds. Wat. Res. 17, 173-183.
9. Masten S. and Hoigné J. (1992) Comparison of ozone and hydroxyl radical-induced oxidation of chlorinated hydrocarbons in water. Ozone Sci. Engng. 14, 197-214.
10. Mertens R. (1994) Photochemistry and radiation chemistry of chlorinated organic compounds in aqueous solution. Ph.D. Thesis, Ruhr-University, Bochum, Germany.
11. Mertens R. and von Sonntag C. (1995) Photolysis (λ = 254 nm) of tetrachloroethene in aqueous solutions. J. Photochem. Photobiol. A: Chem. 85, 1-9.
12. Neta P., Huie R. E. and Ross A. B. (1988) Rate constants for reactions of inorganic radicals in aqueous solutions. J. Phys. Chem. Ref. Data 17, 1027-1284.
13. Staehelin J. and Hoigné J. (1985) Decomposition of ozone in water in the presence of organic solutes acting as promotors and inhibitors of radical chain reactions. Environ. Sci. Technol. 19, 1206-1213.
14. Sunder M. and Hempel D. C. (1996) Reaction-kinetic description of the oxidation of perchloroethylene with ozone and hydrogen peroxide in a tubular reactor. Chem. Ing. Tech. 68, 150-155.
15. Tomiyasu H., Fukutomi H. and Gordon G. (1985) Kinetics and mechanism of ozone decomposition in basic aqueous solution. Inorg. Chem. 24, 2962-2966.
16. Wagner R. and Ruck W. (1984) Determination of hydrogen peroxide and other peroxy-compounds. Z. Wasser-Abwasser-Forsch. 17, 262-267.