Preparation and structure of new diazaselenuranes. Transannular hypervalent bond between seleno and diamino groups

Tetrahedron

Volumn 52, Issue 44, 1996, Pages 13951-13960

  Fujihara, Hisashi ^a,b   Mima, Hisatomo ^a   Furukawa, Naomichi ^a  

^a UNIVERSITY OF TSUKUBA   (Japan)

^b KINKI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOSELENIUM DERIVATIVE;

ARTICLE; DRUG STRUCTURE; DRUG SYNTHESIS; NUCLEAR MAGNETIC RESONANCE; PRIORITY JOURNAL; X RAY ANALYSIS;

EID: 0030605178     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4020(96)00857-5     Document Type: Article

References (18)

1. 1. For a review: Hayes, R. A.; Martin, J. C. 'Sulfurane Chemistry' In Organic Sulfur Chemistry, Theoretical and Experimental Advances; Bernardi, F.; Csizmadia, I. G.; Mangini, A., Eds.; Elsevier: Amsterdam, 1985; Chapter 8.
2. 2. (a) 'The Chemistry of Organic Selenium and Tellurium Compounds'; Patai, S.; Rappoport, Z., Eds.; Wiley: New York, 1986; vol. 1, 1987; vol. 2. The term selenurane (selenane) has been used for tetracoordinate selenium (IV) compounds.
3. (b) 'Selenium Reagents and Intermediates in Organic Synthesis'; Paulmier, C. Pergamon Press, 1986.
4. 3. Fujihara, H.; Mima, H.; Ikemori, M.; Furukawa, N. J. Am. Chem. Soc. 1991, 113, 6337-6338.
5. 4. Fujihara, H.; Mima, H.; Erata, T.; Furukawa, N. J. Am. Chem. Soc. 1993, 115, 9826-9827.
6. 5. Gellatly, R. P.; Ollis, W. D.; Sutherland, I. O. J. Chem. Soc., Perkin Trans 1, 1976, 913-925; Brieaddy, L. E.; Hurlbert, B. S.; Mehta, N. B. J. Org. Chem. 1981, 46, 1630-1634.
7. 5. Gellatly, R. P.; Ollis, W. D.; Sutherland, I. O. J. Chem. Soc., Perkin Trans 1, 1976, 913-925; Brieaddy, L. E.; Hurlbert, B. S.; Mehta, N. B. J. Org. Chem. 1981, 46, 1630-1634.
8. 6. Fujihara, H.; Oi, N.; Akaishi, R.; Kawai, T.; Furukawa, N. Heterocycles, 1989, 29, 441-444
9. 7. Dunstan, S.; Henbest, H. B. J. Chem. Soc., 1957, 4905-4908.
10. 9
11. 9. Levy, G. C.; Lichter, R. L. Nitrogen-15 Nuclear Magnetic Resonance Spectroscopy; John Wiley & Sons, New York, 1979.
12. 9
13. 10
14. 77Se NMR spectra are described: Chapter 6 of Ref. 2a.
15. 14N bond of 4.
16. 15N was negligible in this case.
17. 14. Girard, P.; Namy, J. L.; Kagan, H. B. J. Am. Chem. Soc. 1980, 102, 2693-2698; Soderquist, J. A. Aldrichimica Acta, 1991, 24, 15-23.
18. 14. Girard, P.; Namy, J. L.; Kagan, H. B. J. Am. Chem. Soc. 1980, 102, 2693-2698; Soderquist, J. A. Aldrichimica Acta, 1991, 24, 15-23.