Difluorination of 2-substituted 1,1,1-tris(methylthio)ethanes by oxidative desulfurization-fluorination. A new route to partially fluorinated olefins

Tetrahedron Letters

Volumn 37, Issue 44, 1996, Pages 7983-7986

  Furuta, Satoru ^a   Hiyama, Tamejiro ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOFLUORINE DERIVATIVE;

ARTICLE; DRUG SYNTHESIS; REACTION ANALYSIS;

EID: 0030605160     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(96)01788-1     Document Type: Article

References (12)

1. 1. Kuroboshi, M.; Hiyama, T. Yuki Gosei Kagaku Kyokai Shi 1993, 51, 1124-1133 and references cited therein.
2. 2. a) Biomedical Aspects of Fluorine Chemistry, Filler, R.; Kobayashi, Y., Ed.; Kodansha Ltd. and Elsevier Biomedical: Tokyo and Amsterdam, 1982.
3. b) Kobayashi, Y.; Kumadaki, I. Acc. Chem. Res. 1978, 11, 197-204.
4. c) Hansch, C.; Leo, A. Substituent Constants for Correlation Analysis in Chemistry and Biology; John Wiley and Sons, Inc.: New York, 1979.
5. d) Kusumoto, T.; Hiyama, T.; Takehara, S. Dyestuffs & Chemicals 1994, 39, 6-17.
6. 3. Matthews, D. P.; Whitten, J. P.; McCarthy, J. R. Tetrahedron Lett. 1986, 27, 4861-4864.
7. 4. Kuroboshi, M.; Furuta, S.; Hiyama, T. Tetrahedron Lett. 1995, 36, 6121-6122.
8. 5. Barbero, M.; Cadamuro, S.; Degani, I.; Dughera, S.; Fochi, R. J. Chem. Soc. Perkin Trans. 1 1993, 2075-2080.
9. 4, filtered, and concentrated under reduced pressure. The residue was purified by silica gel column chromatography or thin layer chromatography.
10. 7. Kim, K.; McCarthy, J. R. Tetrahedron Lett. 1996, 37, 3223-3226.
11. 8. Clark, J. H. Chem. Rev. 1980, 80, 429-452.
12. 9. Kuroboshi, M.; Hiyama, T. Bull. Chem. Soc. Jpn. 1995, 68, 1799-1805.