Chiral auxiliary-induced stereocontrol in intramolecular Pauson-Khand reactions leading to angular triquinanes

Tetrahedron

Volumn 52, Issue 44, 1996, Pages 14021-14040

  Tormo, Jordi ^a   Verdaguer, Xavier ^a   Moyano, Albert ^a   Pericàs, Miquel A ^a   Riera, Antoni ^a  

^a UNIVERSITY OF BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

POLYCYCLIC HYDROCARBON;

ARTICLE; CHIRALITY; DRUG SYNTHESIS; PRIORITY JOURNAL; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0030605135     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4020(96)00844-7     Document Type: Article

References (46)

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40. 14.-This compound was prepared through a three-step sequence involving: a) alkylation of the lithium enolate of tert-butyl acetate with bromide 6, b) reduction of the resulting ester with DIBAL, and c) reaction with methyltriphenoxyphosphonium iodide (see experimental section).
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46. 18.-Calculations performed with the PM3 (tm) semiempirical MO program, as implemented in Spartan 4.1.1 (Wavefunction, Inc.).