Synthesis and X-ray crystal structures of the cyclic oxacarbene complexes [Ru{CCH2(CH2)nCH2O}(Ph2PCH2CH2PPh2)(η-C5H5)][PF6](n = 1 or 2): Boat conformation of the 2-oxacyclohexylidene ligand

Journal of Organometallic Chemistry

Volumn 526, Issue 2, 1996, Pages 371-378

  Beddoes, Roy L ^a   Grime, Richard W ^a   Hussain, Zafar I ^a   Whiteley, Mark W ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

Carbene; Crystal structure; Cyclopentadienyl; Ruthenium

Indexed keywords

EID: 0030604324     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(96)06585-0     Document Type: Article

References (20)

1. [1] S.G. Davies, J.P. McNally and A.J. Smallridge, Adv. Organomet. Chem., 30 (1990) 1.
2. [2] M.I. Bruce, Chem. Rev., 91 (1991) 197.
3. [3] N.M. Kostic and R.F. Fenske, Organometallics, 1 (1982) 974.
4. [4] R.L. Beddoes, C. Bitcon, R.W. Grime, A. Ricalton and M.W. Whiteley, J. Chem. Soc. Dalton Trans., (1995) 2873.
5. [5] R.L. Beddoes, R.W. Grime, Z.I. Hussain and M.W. Whiteley, J. Chem. Soc., Dalton Trans., (1996) 3893.
6. [6] G. Consiglio, F. Morandini, G.F. Ciani and A. Sironi, Organometallics, 5 (1986) 1976.
7. [7] M.I. Bruce, G.A. Koutsantonis and E.R.T. Tiekink, Acta Crystallogr. Sect. C:, 44 (1988) 1130.
8. [8] M.I. Bruce, M.G. Humphrey, M.R. Snow and E.R.T. Tiekink, J. Organomet. Chem., 314 (1986) 213.
9. [9] P. Nombel, N. Lugan and R. Mathieu, J. Organomet. Chem., 503 (1995) C22.
10. [10] B.E.R. Schilling, R. Hoffmann and J.W. Faller, J. Am. Chem. Soc., 101 (1979) 592.
11. [11] M.I. Bruce, A.G. Swincer, B.J. Thomson and R.C. Wallis, Aust. J. Chem., 33 (1980) 2605.
12. [12] J.-A.M. Garner, A. Irving and J.R. Moss, Organometallics, 9 (1990) 2836.
13. [13] J.-A.M. Andersen, S.J. Archer, J.R. Moss and M.L. Niven, Inorg. Chim. Acta, 206 (1993) 187.
14. [14] C. Kelley, N. Lugan, M.R. Terry, G.L. Geoffroy, B.S. Haggerty and A.L. Rheingold, J. Am. Chem. Soc., 114 (1992) 6735.
15. [15] M.I. Bruce, C. Dean, D.N. Duffy, M.G. Humphrey and G.A. Koutsantonis, J. Organomet. Chem., 295 (1985) C40.
16. [16] H. Adams, N.A. Bailey, M. Grayson, C. Ridgway, A.J. Smith, P. Taylor and M.J. Winter, Organometallics, 9 (1990) 2621.
17. [17] J.F. McConnell, A.McL. Mathieson and B.P. Schoenborn, Tetrahedron Lett., (1962) 445.
18. [18] G.S. Ashby, M.I. Bruce, I.B. Tomkins and R.C. Wallis, Aust. J. Chem., 32 (1979) 1003.
19. [19] D.T. Cromer and J.T. Waber, International Tables for X-Ray Crystallography, Vol. 4, Kynoch Press, Birmingham, 1974.
20. [20] TEXSAN-TEXRAY, Structure analysis package, 1985 (Molecular Structure Corporation, The Woodlands, TX).