Palladium-catalysed oligocyclisations of 2-bromododeca-1,11-diene-6-ynes

Tetrahedron

Volumn 52, Issue 35, 1996, Pages 11545-11578

  Henniges, Hans ^a,b   Meyer, Frank E ^a,b   Schick, Ute ^a   Funke, Frank ^a,b   Parsons, Philip J ^b   De Meijere, Armin ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

^b UNIVERSITY OF SUSSEX   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOHEXANE DERIVATIVE; INDAN DERIVATIVE; POLYCYCLIC HYDROCARBON;

ARTICLE; CATALYSIS; CHIRALITY; CYCLIZATION; DRUG SYNTHESIS; PRIORITY JOURNAL; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0030603135     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4020(96)00641-2     Document Type: Article

References (63)

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2. For preliminary results of this report see also: (b) Meyer, F. E.; Parsons, P. J.; de Meijere, A. J. Org. Chem. 1991, 56, 6487-6488.
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55. 22. With a methoxycarbonyl or cyano instead of a phenyl group on the cyclisation precursor, epimerisation of the newly formed stereocenters was observed. Cf. ref. [8c].
56. 23. A n-butyl and even a methyl group cis to the bromine prevents the anticipated 6π-electrocyclisation completely. (a) Henniges, H. Dissertation, Universität Göttingen 1994.
57. (b) Cf. ref. [1a].
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62. 28. The authors are indebted to Dr. Matthias Noltemeyer, Institut für Anorganische Chemie, Universität Göttingen, for carrying out this structure analysis. (a) Further details of this crystal structure investigation are available on request from the Fachinformationszentrum Energie Physik Mathematik GmbH, D-76344 Eggenstein-Leopoldshafen, on quoting the depository number CSD-405246, the names of the authors, and the journal citation.
63. (b) Sheldrick, G. M., SHELXTL-PLUS: Program for Crystal Structure Determination, University of Göttingen, 1986.