Reactivity of 17- and 19-electron organometallic complexes.Formation of bent sandwich 19-electron radical cation complexes of osmium and ruthenium

Journal of Organometallic Chemistry

Volumn 519, Issue 1-2, 1996, Pages 1-5

  Kukharenko, S V ^a   Strelets, V V ^a   Kudinov, A R ^b   Kreidlin, A Z ^b   Peterleitner, M G ^b   Denisovich, L I ^b   Rybinskaya, M I ^b  

^a SEMENOV INSTITUTE OF CHEMICAL PHYSICS   (Russian Federation)

^b A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

Author keywords

Cyclopentadienyl; Electrochemistry; Indenyl; Osmium; Ruthenium

Indexed keywords

EID: 0030602714     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(95)06102-9     Document Type: Article

References (21)

1. Strelets V.V. Coord. Chem. Rev. 114:1992;1.
2. Denisovich L.I., Peterleitner M.G., Kravtsov D.N., Kreindlin A.Z., Fadeeva S.S., Rybinskaya M.I. Metalloorg. Khim. 1:1989;301. in Russian.
3. Treichel P.M., Johnson J.W., Wagner K.P. J. Organomet. Chem. 88:1975;227.
4. Kukharenko S.V., Strelets V.V., Ustynyuk N.A., Novikova L.N., Peterleitner M.G., Denisovich L.I. Metalloorg. Khim. 4:1991;299. in Russian.
5. Novikova L.N., Ustynyuk N.A., Denisovich L.I., Peterleitner M.G., Kukharenko S.V., Strelets V.V., Oprunenko Yu.F. Metalloorg. Khim. 4:1991;871. in Russian.
6. Gassman P.O., Winter C.H. J. Am. Chem. Soc. 110:1988;6130.
7. The degree of chemical reversibility of the oxidation process depends on the nature of both the ligand and the metal, other conditions being the same. Thus, reversible oxidation of I, II and IV is observed at room temperature, whereas complex II oxidizes reversibly only at T < -20°C.
8. Gutmann V. The Donor-Acceptor Approach to Molecular Interactions. 1978;Plenum Press, New York.
9. Zhang Y., Gosser D.K., Reiger P.H., Sweigart D.A. J. Am. Chem. Soc. 113:1991;4062.
10. Koelle U.J. Organomet. Chem. 289:1985;133.
11. Smith T.P., Kwan K.S., Taube H., Bino A., Cohen S. Inorg. Chem. 23:1984;1943.
12. Droege M.W., Harman W.D., Taube H. Inorg. Chem. 26:1987;1309.
13. Smith T.P., Iverson D.J., Droege M.W., Kwan K.S., Taube H. Inorg. Chem. 26:1987;2882.
14. Sohn Y.S., Schlueter A.W., Hendrickson D.N., Gray H.B. Inorg. Chem. 13:1974;301.
15. Gale R.J., Job R. Inorg. Chem. 20:1981;42.
16. Hill M.G., Lamanna W.M., Mann K.R. Inorg. Chem. 30:1992;4687.
17. Kukharenko S.V., Bezrukova A.A., Rubezhov A.Z., Strelets V.V. Metalloorg. Khim. 3:1990;634. in Russian.
18. Heinze J. J. Am. Chem. Soc. 112:1990;5142.
19. Coetzee J.F., Martin M.W. Coetzee J.F. Recommended Methods of Purification of Solvents and Tests for Impurities. 1989;Pergamon Press.
20. Crossley N.S., Green J.C., Nagy A., Stringer G. J. Chem. Soc., Dalton Trans. 1989;2139.
21. Kudinov A.R., Rybinskaya M.I. Metalloorg. Khim. 1:1988;1429. in Russian.