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85030208596
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note
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3N-MeOH, r.t. over night, quant.
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16
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0343239904
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18
-
-
85030201932
-
-
note
-
2), 1.08 and 1.01 (broad signal and d, octyl methylene and H-6‴), and 0.66 (t, 3H, octyl methyl).
-
-
-
-
19
-
-
85030204171
-
-
note
-
2O, r.t., 20 min., 89%.
-
-
-
-
20
-
-
85030199299
-
-
note
-
12. During the activation of fluoride 5 under Suzuki's conditions, partial adsorption of acceptor molecule carrying phenylthio group was observed. It seemed that this happened in the case that reaction was carried out in the presence of molecular sieves 4Å. No further activation of fluoride was observed after adsorption. In the case of glycosylation of phenyl 2,3,4-tri-O-benzoyl-1-thio-β-D-galactopyranoside with corresponding fluoride donor (data not shown), adsorption of the product was observed. The thioglycosides adsorbed on MS 4Å was released during aqueous work-up and were recovered quantitatively.
-
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21
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84981673044
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0023656192
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