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Volumn 37, Issue 26, 1996, Pages 4551-4554

Orthogonal glycosylation strategy in synthesis of extended blood group B determinant

Author keywords

[No Author keywords available]

Indexed keywords

GLYCOLIPID; GLYCOSYLTRANSFERASE; OLIGOSACCHARIDE;

EID: 0030600180     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(96)00901-X     Document Type: Article
Times cited : (44)

References (23)
  • 6
    • 0002429383 scopus 로고    scopus 로고
    • Use of Glycosyltransferases in the Synthesis of Unnatural Oligosaccharide Analogues
    • Khan, S. H.; O'Neill, R. A. Eds., Harwood Academic Publishers, United States
    • (f) Crawley, S. C.; Palcic, M. M. "Use of Glycosyltransferases in the Synthesis of Unnatural Oligosaccharide Analogues", in Modern Methods in Carbohydrate Synthesis, Khan, S. H.; O'Neill, R. A. Eds., Harwood Academic Publishers, United States, 1996, pp492-517.
    • (1996) Modern Methods in Carbohydrate Synthesis , pp. 492-517
    • Crawley, S.C.1    Palcic, M.M.2
  • 15
    • 85030208596 scopus 로고    scopus 로고
    • note
    • 3N-MeOH, r.t. over night, quant.
  • 18
    • 85030201932 scopus 로고    scopus 로고
    • note
    • 2), 1.08 and 1.01 (broad signal and d, octyl methylene and H-6‴), and 0.66 (t, 3H, octyl methyl).
  • 19
    • 85030204171 scopus 로고    scopus 로고
    • note
    • 2O, r.t., 20 min., 89%.
  • 20
    • 85030199299 scopus 로고    scopus 로고
    • note
    • 12. During the activation of fluoride 5 under Suzuki's conditions, partial adsorption of acceptor molecule carrying phenylthio group was observed. It seemed that this happened in the case that reaction was carried out in the presence of molecular sieves 4Å. No further activation of fluoride was observed after adsorption. In the case of glycosylation of phenyl 2,3,4-tri-O-benzoyl-1-thio-β-D-galactopyranoside with corresponding fluoride donor (data not shown), adsorption of the product was observed. The thioglycosides adsorbed on MS 4Å was released during aqueous work-up and were recovered quantitatively.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.