A new dinuclear rhodium(III) 'sandwich' polyoxometalate, [(WZnRh2/(III))(ZnW9O34)2]10-. Synthesis, characterization and catalytic activity

Journal of Molecular Catalysis A: Chemical

Volumn 114, Issue 1-3, 1996, Pages 169-180

  Neumann, Ronny ^a   Khenkin, Alexander M ^a  

^a HEBREW UNIVERSITY OF JERUSALEM   (Israel)

Author keywords

Epoxidation; Hydrogen peroxide activation; Rhodium polyoxometalate

Indexed keywords

EID: 0030599591     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1381-1169(96)00315-9     Document Type: Article

References (56)

1. [1] M.T. Pope. Hetetopoly and Isopoly Oxymetallates (Springer Verlag, New York, 1983).
2. [2] M.T. Pope and A. Müller, Angew. Chem., Int. Ed. Engl. 30 (1991) 34: Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity (Kluwer, The Netherlands, 1993).
3. [2] M.T. Pope and A. Müller, Angew. Chem., Int. Ed. Engl. 30 (1991) 34: Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity (Kluwer, The Netherlands, 1993).
4. [3] V.W. Day and W.G. Klemperer, Science 228 (1985) 533; M.T. Pope, Prog, Inorg. Chem. 39 (1991) 181; J. Zubieta and Q. Chen. Coord. Chem. Rev. 114 (1992) 107; K. Isobe and A. Yagasaki, Acc. Chem. Res. 26 (1993) 524.
5. [3] V.W. Day and W.G. Klemperer, Science 228 (1985) 533; M.T. Pope, Prog, Inorg. Chem. 39 (1991) 181; J. Zubieta and Q. Chen. Coord. Chem. Rev. 114 (1992) 107; K. Isobe and A. Yagasaki, Acc. Chem. Res. 26 (1993) 524.
6. [3] V.W. Day and W.G. Klemperer, Science 228 (1985) 533; M.T. Pope, Prog, Inorg. Chem. 39 (1991) 181; J. Zubieta and Q. Chen. Coord. Chem. Rev. 114 (1992) 107; K. Isobe and A. Yagasaki, Acc. Chem. Res. 26 (1993) 524.
7. [3] V.W. Day and W.G. Klemperer, Science 228 (1985) 533; M.T. Pope, Prog, Inorg. Chem. 39 (1991) 181; J. Zubieta and Q. Chen. Coord. Chem. Rev. 114 (1992) 107; K. Isobe and A. Yagasaki, Acc. Chem. Res. 26 (1993) 524.
8. [4] E. Papaconstantinou, Chem. Soc. Rev. 18 (1989) 1; C.L. Hill and C.M. Prosser-McCartha, in: Photosensitization and Pholocatalysis Using Inorganic and Organmetallic Complexes. K. Kalyanasundaram and M. Grätzel (Eds.) (Kluwer, The Netherlands, 1993) p. 307.
9. [4] E. Papaconstantinou, Chem. Soc. Rev. 18 (1989) 1; C.L. Hill and C.M. Prosser-McCartha, in: Photosensitization and Pholocatalysis Using Inorganic and Organmetallic Complexes. K. Kalyanasundaram and M. Grätzel (Eds.) (Kluwer, The Netherlands, 1993) p. 307.
10. [5] M. Misono, Catal. Rev. Sci. Eng. 29 (1987) 269: I.V. Kozhevnikov, Russ. Chem. Rev. 56 (1987) 811; Catal. Rev. Sci. Eng. 37 (1995) 311; N. Mizuno and M. Misono, J. Mol. Catal 86 (1994) 319; I.V. Kozhevnikov and K.I. Matveev. Appl. Catal. 5 (1983) 135; Y. Ishii and M. Ogawa, Reviews on Heteroatom Chemistry, S. Oae (Ed.) (MYU, Tokyo, 1990); C.L. Hill and C.M. Prosser-Mccartha, Coord. Chem. Rev. 143 (1995) 407.
11. [5] M. Misono, Catal. Rev. Sci. Eng. 29 (1987) 269: I.V. Kozhevnikov, Russ. Chem. Rev. 56 (1987) 811; Catal. Rev. Sci. Eng. 37 (1995) 311; N. Mizuno and M. Misono, J. Mol. Catal 86 (1994) 319; I.V. Kozhevnikov and K.I. Matveev. Appl. Catal. 5 (1983) 135; Y. Ishii and M. Ogawa, Reviews on Heteroatom Chemistry, S. Oae (Ed.) (MYU, Tokyo, 1990); C.L. Hill and C.M. Prosser-Mccartha, Coord. Chem. Rev. 143 (1995) 407.
12. [5] M. Misono, Catal. Rev. Sci. Eng. 29 (1987) 269: I.V. Kozhevnikov, Russ. Chem. Rev. 56 (1987) 811; Catal. Rev. Sci. Eng. 37 (1995) 311; N. Mizuno and M. Misono, J. Mol. Catal 86 (1994) 319; I.V. Kozhevnikov and K.I. Matveev. Appl. Catal. 5 (1983) 135; Y. Ishii and M. Ogawa, Reviews on Heteroatom Chemistry, S. Oae (Ed.) (MYU, Tokyo, 1990); C.L. Hill and C.M. Prosser-Mccartha, Coord. Chem. Rev. 143 (1995) 407.
13. [5] M. Misono, Catal. Rev. Sci. Eng. 29 (1987) 269: I.V. Kozhevnikov, Russ. Chem. Rev. 56 (1987) 811; Catal. Rev. Sci. Eng. 37 (1995) 311; N. Mizuno and M. Misono, J. Mol. Catal 86 (1994) 319; I.V. Kozhevnikov and K.I. Matveev. Appl. Catal. 5 (1983) 135; Y. Ishii and M. Ogawa, Reviews on Heteroatom Chemistry, S. Oae (Ed.) (MYU, Tokyo, 1990); C.L. Hill and C.M. Prosser-Mccartha, Coord. Chem. Rev. 143 (1995) 407.
14. [5] M. Misono, Catal. Rev. Sci. Eng. 29 (1987) 269: I.V. Kozhevnikov, Russ. Chem. Rev. 56 (1987) 811; Catal. Rev. Sci. Eng. 37 (1995) 311; N. Mizuno and M. Misono, J. Mol. Catal 86 (1994) 319; I.V. Kozhevnikov and K.I. Matveev. Appl. Catal. 5 (1983) 135; Y. Ishii and M. Ogawa, Reviews on Heteroatom Chemistry, S. Oae (Ed.) (MYU, Tokyo, 1990); C.L. Hill and C.M. Prosser-Mccartha, Coord. Chem. Rev. 143 (1995) 407.
15. [5] M. Misono, Catal. Rev. Sci. Eng. 29 (1987) 269: I.V. Kozhevnikov, Russ. Chem. Rev. 56 (1987) 811; Catal. Rev. Sci. Eng. 37 (1995) 311; N. Mizuno and M. Misono, J. Mol. Catal 86 (1994) 319; I.V. Kozhevnikov and K.I. Matveev. Appl. Catal. 5 (1983) 135; Y. Ishii and M. Ogawa, Reviews on Heteroatom Chemistry, S. Oae (Ed.) (MYU, Tokyo, 1990); C.L. Hill and C.M. Prosser-Mccartha, Coord. Chem. Rev. 143 (1995) 407.
16. [5] M. Misono, Catal. Rev. Sci. Eng. 29 (1987) 269: I.V. Kozhevnikov, Russ. Chem. Rev. 56 (1987) 811; Catal. Rev. Sci. Eng. 37 (1995) 311; N. Mizuno and M. Misono, J. Mol. Catal 86 (1994) 319; I.V. Kozhevnikov and K.I. Matveev. Appl. Catal. 5 (1983) 135; Y. Ishii and M. Ogawa, Reviews on Heteroatom Chemistry, S. Oae (Ed.) (MYU, Tokyo, 1990); C.L. Hill and C.M. Prosser-Mccartha, Coord. Chem. Rev. 143 (1995) 407.
17. [6] R.A. Sheldon, Chem. Eng. Prog. (1991) 411.
18. [7] L.C.W. Baker and T.P McCutcheon, J. Am. Chem. Soc. 78 (1956) 4505; L.C.W, Baker, G.A. Gallagher and T.P. McCutcheon, J. Am. Chem. Soc. 75 (1953) 2493.
19. [7] L.C.W. Baker and T.P McCutcheon, J. Am. Chem. Soc. 78 (1956) 4505; L.C.W, Baker, G.A. Gallagher and T.P. McCutcheon, J. Am. Chem. Soc. 75 (1953) 2493.
20. [8] L. Eberson, J. Am. Chem. Soc. 105 (1983) 3192; L. Eberson and L.-G. Wistrand, Acta Chem. Scand. B 34 (1980) 349; L. Eberson and L. Jönsson. Acta Chem. Scand. B 40 (1986) 79.
21. [8] L. Eberson, J. Am. Chem. Soc. 105 (1983) 3192; L. Eberson and L.-G. Wistrand, Acta Chem. Scand. B 34 (1980) 349; L. Eberson and L. Jönsson. Acta Chem. Scand. B 40 (1986) 79.
22. [8] L. Eberson, J. Am. Chem. Soc. 105 (1983) 3192; L. Eberson and L.-G. Wistrand, Acta Chem. Scand. B 34 (1980) 349; L. Eberson and L. Jönsson. Acta Chem. Scand. B 40 (1986) 79.
23. [9] F. Zonnevijlle, C.M. Tourné and G.F. Tourné, Inorg. Chem. 21 (1982) 2242; 22 (1983) 1198; T.J.R. Weakley and S.A. Malik, J. Inorg. Nucl. Chem. 29 (1967) 2935; S.A. Malik and T.J.R. Weakley, J. Chem. Soc. A (1968) 2647; C.M. Tourné and G.F. Tourné, J. Bull. Soc. Chim. France. (1969) 1124.
24. [9] F. Zonnevijlle, C.M. Tourné and G.F. Tourné, Inorg. Chem. 21 (1982) 2242; 22 (1983) 1198; T.J.R. Weakley and S.A. Malik, J. Inorg. Nucl. Chem. 29 (1967) 2935; S.A. Malik and T.J.R. Weakley, J. Chem. Soc. A (1968) 2647; C.M. Tourné and G.F. Tourné, J. Bull. Soc. Chim. France. (1969) 1124.
25. [9] F. Zonnevijlle, C.M. Tourné and G.F. Tourné, Inorg. Chem. 21 (1982) 2242; 22 (1983) 1198; T.J.R. Weakley and S.A. Malik, J. Inorg. Nucl. Chem. 29 (1967) 2935; S.A. Malik and T.J.R. Weakley, J. Chem. Soc. A (1968) 2647; C.M. Tourné and G.F. Tourné, J. Bull. Soc. Chim. France. (1969) 1124.
26. [9] F. Zonnevijlle, C.M. Tourné and G.F. Tourné, Inorg. Chem. 21 (1982) 2242; 22 (1983) 1198; T.J.R. Weakley and S.A. Malik, J. Inorg. Nucl. Chem. 29 (1967) 2935; S.A. Malik and T.J.R. Weakley, J. Chem. Soc. A (1968) 2647; C.M. Tourné and G.F. Tourné, J. Bull. Soc. Chim. France. (1969) 1124.
27. [9] F. Zonnevijlle, C.M. Tourné and G.F. Tourné, Inorg. Chem. 21 (1982) 2242; 22 (1983) 1198; T.J.R. Weakley and S.A. Malik, J. Inorg. Nucl. Chem. 29 (1967) 2935; S.A. Malik and T.J.R. Weakley, J. Chem. Soc. A (1968) 2647; C.M. Tourné and G.F. Tourné, J. Bull. Soc. Chim. France. (1969) 1124.
28. [10] D.E. Katsoulis and M.T. Pope, J. Am. Chem. Soc. 106 (1984) 2737.
29. [11] D.E. Katsoulis and M.T. Pope, J. Chem. Soc., Chem. Commun. (1986) 1186; A.M. Khenkin and C.L. Hill, J. Am. Chem. Soc. 115 (1993) 8178.
30. [11] D.E. Katsoulis and M.T. Pope, J. Chem. Soc., Chem. Commun. (1986) 1186; A.M. Khenkin and C.L. Hill, J. Am. Chem. Soc. 115 (1993) 8178.
31. [12] C. Rong and M.T. Pope, J. Am. Chem. Soc. 114 (1992) 2932; W.J. Randall, T.J.R. Weakley and R.G. Finke, Inorg. Chem. 32 (1993) 1068.
32. [12] C. Rong and M.T. Pope, J. Am. Chem. Soc. 114 (1992) 2932; W.J. Randall, T.J.R. Weakley and R.G. Finke, Inorg. Chem. 32 (1993) 1068.
33. [13] C.L. Hill and R.B. Brown, J. Am. Chem. Soc. 108 (1986) 536.
34. [14] D. Mansuy, J.-F. Bartoli, P. Battioni, D.K. Lyon and R.G. Finke, J. Am. Chem. Soc. 113 (1991) 7222.
35. [15] M. Faraj and C.L. Hill, J. Chem. Soc., Chem. Commun. (1987) 1487.
36. [16] N. Mizuno, T. Hirose, M. Tateishi and M. Iwamoto, Chem. Lett. (1993) 1839.
37. [17] R. Neumann and M. Levin, Stud. Surf. Sci, Catal. 66 (1991) 121.
38. [18] N. Mizuno, T. Hirose, M. Tateishi and M. Iwamoto, Chem. Lett, (1993) 2137; J. Mol. Catal. 88 (1994) L125; J.E. Lyons, J.E. Ellis and V.A. Durante, Stud. Surf. Sci. Catal. 67 (1991) 99.
39. [18] N. Mizuno, T. Hirose, M. Tateishi and M. Iwamoto, Chem. Lett, (1993) 2137; J. Mol. Catal. 88 (1994) L125; J.E. Lyons, J.E. Ellis and V.A. Durante, Stud. Surf. Sci. Catal. 67 (1991) 99.
40. [18] N. Mizuno, T. Hirose, M. Tateishi and M. Iwamoto, Chem. Lett, (1993) 2137; J. Mol. Catal. 88 (1994) L125; J.E. Lyons, J.E. Ellis and V.A. Durante, Stud. Surf. Sci. Catal. 67 (1991) 99.
41. [19] M.K. Harrup and C.L. Hill, Inorg. Chem. 33 (1994) 5448.
42. [20] D.E. Katsoulis and M.T. Pope, J. Chem. Soc., Dalton Trans. (1989) 1483.
43. [21] R. Neumann and C. Abu-Gnim, J. Chem. Soc., Chem. Commun. (1989) 1324; J. Am. Chem. Soc. 112 (1990) 6025; C.L. Hill, A.M. Khenkin, M.S. Weeks and Y. Hou. ACS Symp. Ser. 523 (1993) 67.
44. [21] R. Neumann and C. Abu-Gnim, J. Chem. Soc., Chem. Commun. (1989) 1324; J. Am. Chem. Soc. 112 (1990) 6025; C.L. Hill, A.M. Khenkin, M.S. Weeks and Y. Hou. ACS Symp. Ser. 523 (1993) 67.
45. [21] R. Neumann and C. Abu-Gnim, J. Chem. Soc., Chem. Commun. (1989) 1324; J. Am. Chem. Soc. 112 (1990) 6025; C.L. Hill, A.M. Khenkin, M.S. Weeks and Y. Hou. ACS Symp. Ser. 523 (1993) 67.
46. [22] R. Neumann and M. Dahan, J. Chem. Soc., Chem. Commun. (1995) 171.
47. [23] C.M. Tourné, G.F. Tourné and F. Zonneviijlle, J. Chem. Soc., Dalton Trans. (1991) 143.
48. [24] T.J.R. Wenkley, H.T. Evans, Jr., J.S. Showell, G.F. Tourné and C.F. Tourné, J. Chem. Soc., Chem. Commun. (1973) 139.
49. [25] R.G. Finke and M.W. Froege, Inorg. Chem. 22 (1983) 1006.
50. [26] A.M. Khenkin and C.L. Hill. Mendeleev Commun. (1993) 140; R. Neumann and M. Gara, J. Am. Chem. Soc. 116 (1994) 5509: 117 (1995) 5066.
51. [26] A.M. Khenkin and C.L. Hill. Mendeleev Commun. (1993) 140; R. Neumann and M. Gara, J. Am. Chem. Soc. 116 (1994) 5509: 117 (1995) 5066.
52. [26] A.M. Khenkin and C.L. Hill. Mendeleev Commun. (1993) 140; R. Neumann and M. Gara, J. Am. Chem. Soc. 116 (1994) 5509: 117 (1995) 5066.
53. [27] R. Neumann and A.M. Khenkin, Inorg. Chem. 34 (1995) 5753.
54. [28] R. Neumann, A.M. Khenkin and M. Dahan, Angew. Chem., Int. Engl. Ed. 34 (1995) 1587.
55. [29] F. Zonnevijlle, C.M. Tourne and G.F. Tourne, Inorg. Chem. 21 (1982) 2751.
56. [30] M.T. Pope, private communication.