2-(Acetoxymethyl)-1,1-difluoro-3-(trimethylsilyl)propene: Preparation and utility as a novel bifunctional reagent containing a CF2 group

Tetrahedron Letters

Volumn 37, Issue 30, 1996, Pages 5401-5404

  Shi, Guo Qiang ^a   Huang, Xian Hai ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOFLUORINE DERIVATIVE;

ARTICLE; DRUG SYNTHESIS; FLUORINATION; REACTION ANALYSIS; TECHNIQUE;

EID: 0030598096     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(96)01106-9     Document Type: Article

References (28)

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4. 3. Schirlin, D.; Baltzer, S.; Altenburger, J. M.; Tarnus, C.; Remy, J. M. Tetrahedron 1996, 52, 305 and references cited therein
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21. 9. The base-induced dehydrohalogenation of allyl halides has been used for the preparation of cyclopropenes, Baird, M. S. Top. Curr. Chem. 1988, 144, 137.
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26. 2Si: C 48.65, H 7.21. Found: C 48.73, H 7.06.
27. 2OH was obtained via a 1,4-reduction pathway.
28. 15. Aliphatic aldehydes were found to be unreactive under the same reaction conditions.