The kinetic impact of vinylic fluorine substituents on 5-hexenyl radical cyclizations

Tetrahedron Letters

Volumn 37, Issue 30, 1996, Pages 5321-5324

  Dolbier Jr , William R ^a   Rong, Xiao X ^a  

^a University of Florida   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOFLUORINE DERIVATIVE;

ARTICLE; DRUG SYNTHESIS; REACTION ANALYSIS; TECHNIQUE;

EID: 0030598043     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(96)01120-3     Document Type: Article

References (21)

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9. 9. Dolbier, W. R., Jr. Chem, Rev. 1996, in press.
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11. 11. Low, H. C.; Tedder, J. M.; Walton, J. C. J. Chem. Soc. Faraday Trans. 1976, 72, 1707-1714.
12. 12. Taken from the Ph. D. dissertation of Xiao X. Rong, University of Florida, 1995.
13. 5
14. C for substrates 1-5 are 4.24, 15.9, 12.9, 13.5 and 4.43, respectively.
15. 15. For further details as to experimental procedure see: Rong, X. X.; Pan, H.-Q.; Dolbier, W. R., Jr.; Smart, B. E. J. Am. Chem. Soc. 1994, 116, 4521-4522.
16. 19F NMR spectroscopy, and mass spectrometry.
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18. 18. Smart, B. E. In Molecular Structure and Energetics, Vol. 3: Studies of Organic Molecules; Liebman, J. F.; Greenberg, A., Eds.; VCH: New York, 1986.
19. 19. Paste, D. J.; Krasnansky, R.; Zercher, C. J. Org. Chem. 1987, 52, 3062-3072.
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