Olefin separation using silver impregnated ion-exchange membranes and silver salt/polymer blend membranes

Journal of Membrane Science

Volumn 117, Issue 1-2, 1996, Pages 151-161

  Yamaguchi, Takeo ^a,c   Baertsch, Chelsey ^a   Koval, Carl A ^b   Noble, Richard D ^a   Bowman, Christopher N ^a  

^a UCB 450   (United States)

^b UNIVERSITY OF COLORADO   (United States)

^c UNIVERSITY OF TOKYO   (Japan)

Author keywords

Facilitated transport; Gas separation membrane; Olefin separation; Silver tetrafluoroborate

Indexed keywords

ALKENE; SILVER;

ARTICLE; ARTIFICIAL MEMBRANE; DISSOCIATION CONSTANT; ION EXCHANGE CHROMATOGRAPHY; MEMBRANE; PHASE TRANSITION; PRIORITY JOURNAL;

ION EXCHANGE; MEMBRANES; SEPARATION;

BUTADIENE; BUTANE; BUTENES; DISSOCIATION; GAS PERMEABLE MEMBRANES; HYDROCARBONS; IMPREGNATION; ION EXCHANGE MEMBRANES; OLEFINS; POLYMERIC MEMBRANES; SILVER;

BUTENE SELECTIVITY; DISSOCIATION PRESSURE; DRY FEED BUTENE PRESSURES; FACILITATED TRANSPORT; OLEFIN SEPARATION; SILVER IMPREGNATED ION EXCHANGE MEMBRANES; SILVER SALT POLYMER BLEND MEMBRANES; SILVER TETRAFLUOROBORATE;

SEPARATION;

EID: 0030596633     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/0376-7388(96)00056-7     Document Type: Article

References (21)

1. [1] O.H. LeBlanc, W.J. Ward, S.L. Matson and S.G. Kimura, Facilitated transport in ion-exchange membranes, J. Membrane Sci., 6 (1980) 339.
2. [2] H.H. Funke, R.D. Noble and C.A. Koval, Separation of gaseous olefin isomers using facilitated transport membranes, J. Membrane Sci., 82 (1993) 229.
3. [3] O.I. Ericksen, E. Aksnes and I.M. Dahl, Facilitated transport of ethene through Nafion membranes. Part 2. Glycerin treated, water swollen membranes, J. Membrane Sci., 85 (1993) 99.
4. [4] J.C. Davis, R.J. Valus, R. Eshraghi and A.E. Velikoff, Facilitated transport membrane hybrid systems for olefin purification, Sep. Sci. Technol., 28 (1993) 463.
5. [5] C. Richter and D. Woermann, Facilitated transport of ethene across polyelectrolyte gels with silver ions as a carrier, J. Membrane Sci., 91 (1994) 217.
6. [6] G.-H. Hsiue and J.-S. Yang. Novel methods in separation of olefin/paraffin mixtures by functional polymeric membranes, J. Membrane Sci., 82 (1993) 117.
7. [7] C.A. Koval and, T. Spontarelli. Condensed phase facilitated transport of olefins through an ion exchange membrane, J. Am. Chem. Soc., 110 (1988) 293.
8. [8] P.M. Thoen, R.D. Noble and C.A. Koval, Unexpectedly large selectivities for olefin separations utilizing silver ion in ion-exchange membranes, J. Phys. Chem., 98 (1994) 1262.
9. [9] C.A. Koval, T. Spontarelli antl R.D. Noble, Styrene/ethylbenzene separation using facilitated transport through perfluorosulfonate ionomer membranes, Ind. Eng. Chem. Res., 28 (1989) 1020.
10. [10] C.A. Koval, T. Spontarelli, P. Thoen and R.D. Noble, Swelling and thickness effects on the separation of styrene and ethylbenzene based on facilitated transport through ionomer membranes, Ind. Eng. Chem. Res., 31 (1992) 1116.
11. +-containing polymer membranes, J. Membrane Sci., 91 (1994) 13.
12. [12] K.-V. Peinemann, S.K. Shukla and M. Schossig, Preparation and properties of highly selective inorganic/organic blend membranes for separation of reactive gases, Proc. ICOM 90, Chicago. IL, 1990, pp. 792.
13. [13] S.K. Shukla and K.-V. Peinemann, The challenge of fixed-carrier facilitated transport - Experiments giving new insights, personal communication, 1992.
14. [14] K.-V. Peinemann, Personal communication, 1992.
15. [15] H.W. Quinn and D.N. Glew. Coordination compounds of olefins with solid complex silver salts, Can. J. Chem., 40 (1962) 1103.
16. [16] H.W. Quinn, Coordination compounds of 1,3-butadiene with anhydrous silver tetrafluoroborate, Can. J. Chem., 45 (1967) 1329.
17. [17] A.W. Francis and N.J., Woodbury, Purification of lower olefins, US Pat., 2498204, February 21, 1950.
18. [18] R. Rabago, Facilitated Transport Through Surfactant-modified and Unmodified Ion Exchange Membranes, Ph.D. Thesis, University of Colorado, 1994.
19. [19] T.A. Zawodzinski. Jr., C. Derourin, S. Radzinski, R.J. Sherman, V.T. Smith, T.E. Springer and S. Gottesfeld, Water uptake by and transport through Nafion 117 membranes, J. Electrochem. Soc., 140 (1993) 1041.
20. [20] J.T. Hinatsu, M. Mizuhata and H. Takenaka. Water uptake of perfluorosulfonic acid membranes from liquid water and water vapor, J. Electrochem. Soc., 141 (1994) 1493.
21. [21] M.D. Heaney and J.J. Pellegrino, Increased facilitation transport related to microstructural changes in heat-treated ion-exchange membranes, J. Membrane Sci., 47 (1989) 143.