Synthesis, characterization and structure of the ethylene-bridged dimer [Cp(CO)2RuCH2CH2Ru(CO)2Cp] and comparison of its reactivity with that of [Cp(CO)2RuCH2CH3] and [Cp(CO)2Ru(CH2)5Ru(CO)2CP]: Models for Fischer-Tropsch surface intermediates

Journal of Organometallic Chemistry

Volumn 510, Issue 1-2, 1996, Pages 233-241

  Gafoor, Mansoor A ^a   Hutton, Alan T ^a   Moss, John R ^a  

^a UNIVERSITY OF CAPE TOWN   (South Africa)

Author keywords

Crystal structure; Cyclopentadienyl; Ethylene; Fischer Tropsch; Ruthenium

Indexed keywords

EID: 0030596359     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(95)05897-X     Document Type: Article

References (40)

1. W. Beck, B. Niemer and M. Wiener, Angew. Chem., Int. Edn. Engl., 32 (1993) 923.
2. C.P. Casey and J. Audett, Chem. Rev., 86 (1986) 339.
3. J.R. Moss and L.G. Scott, Coord. Chem. Rev., 60 (1984) 171.
4. C.K. Rofer-DePoorter, Chem. Rev., 81 (1981) 447.
5. M.E. Dry, Catal. Today, 6 (1990) 183.
6. W.A. Herrmann, Angew. Chem., Int. Edn. Engl., 21 (1982) 117; C. Masters, Adv. Organomet. Chem., 17 (1979) 61.
7. W.A. Herrmann, Angew. Chem., Int. Edn. Engl., 21 (1982) 117; C. Masters, Adv. Organomet. Chem., 17 (1979) 61.
8. F.A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, Wiley, New York, 5th edn., 1988, p. 1229.
9. K.R. Krishna and A.T. Bell, J. Catal., 139 (1993) 104.
10. N.M. Doherty and S.A.R. Knox, Inorg. Synth., 25 (1989) 179.
11. (a) K.P. Finch, J.R. Moss and M.L. Niven, Inorg. Chim. Acta, 166 (1989) 181 and references cited therein;
12. (b) K.P. Finch, M.A. Gafoor, S.F. Mapolie and J.R. Moss, Polyhedron, 10 (1991) 963.
13. J.W. Faller and B.V. Johnson, J. Organomet. Chem., 88 (1975) 101; A.T. Hutton, in J.J. Zuckerman and A.P. Hagen (eds.), Inorganic Reactions and Methods, Vol. 12a, VCH, New York, 1991, pp. 26-32.
14. J.W. Faller and B.V. Johnson, J. Organomet. Chem., 88 (1975) 101; A.T. Hutton, in J.J. Zuckerman and A.P. Hagen (eds.), Inorganic Reactions and Methods, Vol. 12a, VCH, New York, 1991, pp. 26-32.
15. A. Davison, J.A. McCleverty and G. Wilkinson, J. Chem. Soc., (1963) 1133.
16. A.C.T. North, D.C. Phillips and F. Scott Mathews, Acta Crystallogr., Sect. A, 24 (1968) 351.
17. D.T. Cromer and J.B. Mann, Acta Crystallogr., Sect. A, 24 (1968) 321.
18. R.F. Stewart, E.R. Davidson and W.T. Simpson, J. Chem. Phys., 42 (1965) 3175.
19. D.T. Cromer and D. Liberman, J. Chem. Phys., 53 (1970) 1891.
20. G.M. Sheldrick, in H. Schenk, R. Oltof-Hazenkamp, J. van Koningsveld and G.C. Bassi (eds.), Computing in Crystallography, Delft University Press, Delft, 1978, p. 34.
21. J. Galloy and C. Macrae, PLUTO-89 program for Plotting Molecular and Crystal Structures, University of Cambridge, Cambridge, Cambs., 1989.
22. Y.C. Lin, J.C. Calabrese and S.S. Wreford, J. Am. Chem. Soc., 105 (1983) 1679.
23. R.J. Kasluaskas and M.S. Wrighton, Organometallics, 1 (1982) 602.
24. K.A. Mahmoud, A.J. Rest and H.G. Alt, J. Chem. Soc., Dalton Trans., (1985) 1365.
25. J.A.S. Howell and A.J. Rowan, J. Chem. Soc., Dalton Trans., (1980) 1845.
26. M.F. Joseph, J.A. Page and M.C. Baird, Organometallics, 3 (1984) 1749.
27. A. Emeran, M.A. Gafoor, J.K.I. Goslett, Y.-H. Liao, L. Pimble and J.R. Moss, J. Organomet. Chem., 405 (1991) 237.
28. F.H. Allen, O. Kennard, D.G. Watson, L. Brammer, A.G. Orpen and R. Taylor, J. Chem. Soc., Perkin Trans. II, (1987) S1.
29. L. Pope, P. Sommerville, M. Laing, K.J. Hindson and J.R. Moss, J. Organomet. Chem., 112 (1976) 309.
30. A.G. Orpen, L. Brammer, F.H. Allen, O. Kennard, D.G. Watson and R. Taylor, J. Chem. Soc., Dalton Trans., (1989) S1.
31. R.C. Brady and R. Pettit, J. Am. Chem. Soc., 102 (1980) 6182.
32. M.A. Gafoor and J.R. Moss, unpublished work, 1991.
33. R. George, J.M. Andersen and J.R. Moss, J. Organomet. Chem., in press.
34. V. Ponec, Catal. Rev., 18 (1978) 151; H. Pichler and H. Schulz, Chem.-Ing.-Tech., 42 (1970) 1162.
35. V. Ponec, Catal. Rev., 18 (1978) 151; H. Pichler and H. Schulz, Chem.-Ing.-Tech., 42 (1970) 1162.
36. H. Pichler and B. Firnhaber, Brennst.-Chem., 44 (1963) 33; H. Pichler, H. Meier zu Köcker, W. Gabler, R. Gärtner and D. Kionisis, Brennst.-Chem., 48 (1967) 266.
37. H. Pichler and B. Firnhaber, Brennst.-Chem., 44 (1963) 33; H. Pichler, H. Meier zu Köcker, W. Gabler, R. Gärtner and D. Kionisis, Brennst.-Chem., 48 (1967) 266.
38. C.J. Wang and J.G. Ekerdt, J. Catal., 86 (1984) 239.
39. R.O. Hill, C.F. Marais and J.R. Moss, unpublished results, 1995.
40. S.R. Craxford and E.K. Rideal, J. Chem. Soc., (1939) 1604.