Some neutral ruthenium vinylidene complexes and a novel 1,3-elimination reaction: Preparation of chiral ruthenium acetylides

Journal of Organometallic Chemistry

Volumn 522, Issue 2, 1996, Pages 307-310

  Bruce, Michael I ^a   Hall, Ben C ^a   Zaitseva, Natasha N ^a   Skelton, Brian W ^b   White, Allan H ^b  

^a UNIVERSITY OF ADELAIDE   (Australia)

^b UNIVERSITY OF WESTERN AUSTRALIA   (Australia)

Author keywords

Chirality; Crystal structure; Ruthenium; Vinylidene

Indexed keywords

EID: 0030595255     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(96)06200-6     Document Type: Article

References (20)

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3. [2] B.M. Trost, R.J. Kulawiec and A. Hammes, Tetrahedron Lett., 34 (1993) 587; B.M. Trost and R.J. Kulawiec, J. Am. Chem. Soc., 114 (1992) 5579; B.M. Trost, G. Dyker and R.J. Kulawiec, J. Am. Chem. Soc., 112 (1990) 7809.
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11. [8] M.I. Bruce, in G. Wilkinson, F.G.A. Stone and E.W. Abel, (eds.) Comprehensive Organometallic Chemistry, Vol. 4, Pergamon, Oxford, 1982, p. 783.
12. +.
13. diff) being used. Computation used the XTAL 2.6 program system implemented by S.R. Hall [11]; neutral atom complex scattering factors were employed. Atomic coordinates, bond lengths and angles, and thermal parameters have been deposited at the Cambridge Crystallographic Data Centre.
14. [11] S.R. Hall and J.M. Stewart, (eds.) XTAL Users' Manual, Version 2.6, Universities of Western Australia and Maryland, 1989.
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