Efficient method for inversion of secondary alcohols by reaction of chloromethanesulfonates with cesium acetate

Tetrahedron Letters

Volumn 37, Issue 34, 1996, Pages 6145-6148

  Shimizu, Takeshi ^a   Hiranuma, Sayoko ^a   Nakata, Tadashi ^a  

^a RIKEN   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID DERIVATIVE; ALCOHOL; METHYL CHLORIDE; SULFONIC ACID DERIVATIVE;

ARTICLE; MOLECULAR INTERACTION; ORGANIC CHEMISTRY; SYNTHESIS;

EID: 0030593621     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(96)01333-0     Document Type: Article

References (17)

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14. 3. Purchased from Tokyo Cemical Industry Co., Ltd.
15. 2Cl in pyridine affoded a mixture of the corresponding chlorides and chloromethanesulfonates.
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17. 6. Stereochemical assignments of the inverted alcohols and the acetates were made by comparison with the starting alcohols and the acetates.