Mixed organofluorine-organosilicon chemistry. 6. Synthesis of gem-difluoro-C-glycosides and C-disaccharides from acylsilanes and trifluoromethyltrimethylsilane. An exploratory study

Tetrahedron Letters

Volumn 37, Issue 34, 1996, Pages 6115-6116

  Brigaud, Thierry ^a   Lefebvre, Olivier ^a   Plantier Royon, Richard ^a   Portella, Charles ^a  

^a CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

DISACCHARIDE; ORGANOFLUORINE DERIVATIVE; SILANE DERIVATIVE; TRIMETHYLSILYL DERIVATIVE;

ARTICLE; DRUG SYNTHESIS; ENZYME ACTIVATION; ENZYME CHEMISTRY; GLYCOSYLATION; NONHUMAN; OXYGEN CONSUMPTION; REACTION ANALYSIS;

EID: 0030593608     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(96)01305-6     Document Type: Article

References (10)

1. 1/ Postema, M.H.D. Tetrahedron 1992, 48, 8545-8599.
2. 2l Welch, J.T., Eswarakrishnan, S.Fluorine in Bioorganic Chemistry; J. Wiley and Sons, 1991.
3. 3/ Taylor, N.F. Fluorinated carbohydrates: Chemical and Biochemical Aspects; A.C.S. Symposium Series N° 374, Washington D. C., 1988.
4. 4/ Houlton, J.S.; Motherwell, W.B.; Ross, B.C. ;Tozer, M.J.; Williams, D.J.; Slawin, A.M.J. Tetrahedron, 1993, 49, 8087-8106.
5. 5/ Herpin, T.F.; Motherwell, W.B.; Tozer, M.J. Tetrahedron: Asymmetry, 1994, 5, 2269-2282.
6. 6/ Brigaud, T.; Doussot, P.; Portella, C. J. Chem. Soc. Chem. Commun., 1994, 2117-2118.
7. 7/ All new compounds gave satisfactory microanalysis.
8. 13C-NMR (glucal moiety) 74.1 (C-5), 74.4 (C-1).
9. 9/ Dave, D.R.; Fraser-Reid, B. J.Org. Chem. 1984, 49, 522-528.
10. 10/ Plantier-Royon, R.; Portella, C. Tetrahedron Lett., preceeding paper.