Redeterminations of the solid-state structures of trimethylarsenic dibromide, Me3AsBr2, and trimethylantimony dibromide, Me3SbBr2, by X-ray crystallography and solid state 13C MAS NMR evidence for a highly symmetrical D3h, non-ionic structure for Me3SbBr2

Journal of Organometallic Chemistry

Volumn 512, Issue 1-2, 1996, Pages 21-25

  Wang, Hubert C ^a   Gaffney, Edward J ^a   Dybowski, Cecil R ^a   Rheingold, Arnold L ^a  

^a UNIVERSITY OF DELAWARE   (United States)

Author keywords

Antimony; Arsenic; Crystal structure

Indexed keywords

EID: 0030593198     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(95)05879-T     Document Type: Article

References (11)

1. [1] For summaries of these studies, see: G.O. Doak and L.D. Freedman, Organometallic Compounds of Arsenic, Antimony and Bismuth, Wiley, New York, 1970, pp. 205, 333; Gmelin Handbook of Inorganic Chemistry, Organoantimony Compounds, Vol. 4, Springer, Berlin, 1986.
2. [1] For summaries of these studies, see: G.O. Doak and L.D. Freedman, Organometallic Compounds of Arsenic, Antimony and Bismuth, Wiley, New York, 1970, pp. 205, 333; Gmelin Handbook of Inorganic Chemistry, Organoantimony Compounds, Vol. 4, Springer, Berlin, 1986.
3. [2] T.B. Brill and G.G. Long, Inorg. Chem., 9 (1970) 1980.
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6. [5] A.F. Wells, Z. Kryst., 99 (1938) 367.
7. [6] As-Br bond distances were obtained from the Cambridge Structural Database: F.H. Allen and O. Kennard, Chem. Design Automat. News, 8 (1993) 31.
8. [7] W. Schwartz and H.J. Guder, Z. Anorg. Allgem. Chem., 444 (1978) 105.
9. [8] J.G. Hexem, M.H. Frey and S.J. Opella, J. Am. Chem. Soc., 103 (1981) 224.
10. [9] W.J.C. Dyke, G. Davies and W.J. Jones, J. Chem. Soc., (1931) 185.
11. [10] H. Schmidbaur and K.H. Mitschke, Chem. Ber., 104 (1971) 1837.