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The addition of methylmagnesium iodide to the imines derived from (S)- and (R)-1-phenylethanamine and (-)-menthyl glyoxylate (double asymmetric induction, principally dictated by the menthyl group) was reported
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In this preliminary communication the configuration of the amine 4h was erroneously assigned
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3), 136 (67), 91 (23), 119 (20), 255 (17), 120 (12), 77 (10), 105 (10), 269 (3, M+). The mass spectra of all the observed 1,2-diamines 9 had generally the most abundant ions at m/z = (M/2)+. Two unidentified isomeric compounds produced in low yield from 1i had m/z 105 (100), 72 (56), 216 (53), 112 (50), 176 (34), 79 (20), 106 (15), 55 (14), 77 (12).
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23
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0011886447
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