Synthesis and structure of trinuclear methoxy-bridged titanium(III) -magnesium complexes: [(C5H5-nMen)2Ti(μ-OMe)2]2Mg (n = 4 and 5)

Journal of Organometallic Chemistry

Volumn 516, Issue 1-2, 1996, Pages 177-185

  Gyepes, Róbert ^a   Hiller, Jörg ^b   Thewalt, Ulf ^b   Polášek, Miroslav ^a   Šindelář, Pavel ^c   Mach, Karel ^a  

^a J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

^b UNIVERSITY OF ULM   (Germany)

^c Polymer Institute Brno   (Czech Republic)

Author keywords

EPR spectra; Methoxy bridged; Titanium; Titanium(III) magnesium complexes; X ray structure

Indexed keywords

EID: 0030583071     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(96)06126-8     Document Type: Article

References (25)

1. [1] G. Fink, R. Mülhaupt and H.H. Brintzinger (eds.), Ziegler Catalysts, Springer, Berlin and Heidelberg, 1995.
2. [2] L. Malpezzi, U. Zucchini and T. Dall'Occo, Inorg. Chim. Acta, 180 (1991) 245.
3. [3] T. Dall'Occo, F. Sartori, G. Vecellio, U. Zucchini and A. Maldotti, Makromol. Chem., 194 (1993) 151.
4. [4] U. Zucchini, T. Dall'Occo and A. Angelini, J. Mol. Catal., 82 (1993) 45.
5. [5] G. Valle, G. Ruisi and V. Russo, Inorg. Chim. Acta, 82 (1984) 81.
6. [6] P. Sobota, J. Utko and T. Lis, J. Chem. Soc. Dalton Trans., (1984) 2077.
7. [7] L. Brun, Acta Crystallogr., 20 (1966) 739.
8. [8] D.A. Brown and M.G.H. Wallbridge, Inorg. Chim. Acta, 206 (1993) 209.
9. [9] N.J. Clayden and P.J.V. Jones, J. Chem. Soc. Perkin Trans. 2, (1990) 175.
10. [10] G. Giunchi, E. Albizzati, L. Malpezzi and E. Gianetti, Inorg. Chim. Acta, 147 (1988) 159.
11. [11] P. Sobota, M. Wroblewska, S. Szaefert and T. Glowiak, J. Organomet. Chem., 481 (1994) 57.
12. [12] D.W. Stephan, Organometallics, 11 (1992) 996.
13. [13] S.I. Troyanov, V. Varga and K. Mach, J. Organomet. Chem., 461 (1993) 85.
14. [14] S.I. Troyanov, V. Varga and K. Mach, J. Chem. Soc. Chem. Commun., (1993) 1174.
15. [15] R. Gyepes, K. Mach, I. Císařová, J. Loub, J. Hiller and P. Šindelář, J. Organomet. Chem., 497 (1995) 33.
16. [16] H. Antropiusová A. Dosedlová, V. Hanuš and K. Mach, Transition Met. Chem., 6 (1981) 90.
17. [17] R. Brüggemann, T. Debaerdemaeker, B. Müller, G. Schmid and U. Thewalt, ULM-Programmsystem, I. Jahrestagung der Deutschen Gesellschaft für Kristallografie, Mainz, 9-12 June, 1992, Abstr., p. 33 (includes G.M. Sheldrick, SHELX-76 Program for Crystal Structure Determination, University of Cambridge, Cambridge, UK, 1976).
18. [17] R. Brüggemann, T. Debaerdemaeker, B. Müller, G. Schmid and U. Thewalt, ULM-Programmsystem, I. Jahrestagung der Deutschen Gesellschaft für Kristallografie, Mainz, 9-12 June, 1992, Abstr., p. 33 (includes G.M. Sheldrick, SHELX-76 Program for Crystal Structure Determination, University of Cambridge, Cambridge, UK, 1976).
19. [18] A.L. Spek, PLUTON Molecular graphics program, Utrecht University, Netherlands, 1995.
20. [19] E. Samuel, J.F. Harrod, D. Gourier, Y. Dromzee, F. Robert and Y. Jeannin, Inorg. Chem., 31 (1992) 3252.
21. [20] P.T. Moseley and H.M.M. Shearer, J. Chem. Soc. Chem. Commun., (1968) 279.
22. [21] J.L. Atwood and G.D. Stucky, J. Organomet. Chem., 13 (1968) 53.
23. [22] R.L. Belford, N.D. Chasteen, H. So and R.E. Tapscott, J. Am. Chem. Soc., 91 (1969) 4675.
24. [23] D. Gourier, D. Vivien and E. Samuel, J. Am. Chem. Soc., 107 (1985) 7418.
25. [24] M. Horáček, R. Gyepes, V. Varga, I. Císařová and K. Mach, XI. FECHEM Conf. Organomet. Chem., Parma, Italy, 1995, Abstr., p. 89.