Synthesis of 3-alkoxymethyl-4-aryl-3-tert-butyl-4-methoxy-1,2-dioxetanes as a chemiluminescent substrate with short half-life emission

Tetrahedron Letters

Volumn 37, Issue 33, 1996, Pages 5939-5942

  Matsumoto, Masakatsu ^a   Watanabe, Nobuko ^a   Kobayashi, Hisako ^b   Suganuma, Hiroyuki ^a   Matsubara, Jyunya ^a   Kitano, Yoshikazu ^b   Ikawa, Hiroshi ^b  

^a KANAGAWA UNIVERSITY   (Japan)

^b Central Research Laboratories   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

1,2 DIOXETANE DERIVATIVE; ALKALINE PHOSPHATASE;

ARTICLE; CHEMOLUMINESCENCE; ELECTRON TRANSPORT; ENZYME SUBSTRATE; MOLECULAR DYNAMICS; SYNTHESIS; THERMOSTABILITY;

EID: 0030581406     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(96)01282-8     Document Type: Article

References (22)

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10. 9. All the dioxetanes synthesized here gave satisfactory analytical data.
11. 1H-NMR spectrum of the photolysate showed that 2a formed selectively.
12. 11. A similar tendency in selectivity of singlet oxygenation of 1 and 5 has been observed for methoxyphenyl analogues; Matsumoto, M.; Kobayashi, H.; Matsubara, J.; Watanabe, N.; Yamashita, S.; Oguma, D.; Kitano, Y.; Ikawa, H. Tetrehedron Lett. 1996, 37, 397-400.
13. 5 An electron transfer seems to occur when an aromatic ring lies nearly perpendicular to the plane comprising of 2-O, 3-C, and an aromatic carbon attached to the dioxetane for 3-aryldioxetane.
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