Synthesis, molecular structure and reactions of the novel organometallic thioether ligand [WI2(CO){(Me)S(CH2)2S(CH2)SMe-S,S′}(η2-PhC2Ph)]

Journal of Organometallic Chemistry

Volumn 518, Issue 1-2, 1996, Pages 235-237

  Baker, Paul K ^a   Clark, Alec I ^a   Coles, Simon J ^c   Hursthouse, Michael B ^c   Richards, Raymond L ^b  

^a BANGOR UNIVERSITY   (United Kingdom)

^b JOHN INNES CENTRE   (United Kingdom)

^c CARDIFF UNIVERSITY   (United Kingdom)

Author keywords

Crystal structure; Diphenylacetylene; Sulphur; Tungsten

Indexed keywords

EID: 0030581052     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(96)06164-5     Document Type: Article

References (19)

1. [1] J.S. Kim and D.C. Rees, Science, 257 (1992) 1677.
2. [2] W.H. Orme-Johnson, Science, 257 (1992) 1639.
3. [3] J.S. Kim and D.C. Rees, Nature, 360 (1992) 553.
4. [4] T. Yoshida, T. Adachi, M. Kaminaka and T. Ueda, J. Am. Chem. Soc., 110 (1988) 872.
5. [5] T. Adachi, M.C. Durrant, D.L. Hughes, C.J. Pickett, R.L. Richards, J. Talarmin and T. Yoshida, J. Chem. Soc., Chem. Commun., (1992) 1464.
6. [6] M.C. Durrant, D.L. Hughes, R.L. Richards, P.K. Baker and S.D. Harris, J. Chem. Soc., Dalton Trans., (1992) 3399.
7. [7] P.K. Baker, S.D. Harris, M.C. Durrant, D.L. Hughes and R.L. Richards, J. Chem. Soc., Dalton Trans., (1994) 1401.
8. [8] P.K. Baker, M.C. Durrant, B. Goerdt, S.D. Harris, D.L. Hughes and R.L. Richards, J. Organomet. Chem., 469 (1994) C22.
9. [9] P.K. Baker and D.J. Sherlock, J. Organomet. Chem., 13 (1994) 525.
10. [10] P.K. Baker, S.J. Coles, M.B. Hursthouse, M.M. Meehan, and S.D. Ridyard, J. Organomet. Chem., 503 (1995) C8.
11. [11] E.M. Armstrong, P.K. Baker and M.G.B. Drew, Organometallics, 7 (1988) 319.
12. 4).
13. 0) are 0.0684 and 0.0349 respectively. Diagrams were drawn with SNOOPI [18]. Sources of scattering factor data are given in Ref. [17]. Full tables of bond lengths and angles, anisotropic displacement parameters of non-hydrogen atoms, hydrogen atom parameters, and tables of structure factors have been deposited at the Cambridge Crystallographic Data Centre.
14. [14] S.R. Drake, M.B. Hursthouse, K.M.A. Malik and S.A.S. Miller, Inorg. Chem., 32 (1993) 4653.
15. [15] N.P.C. Walker and D. Stuart, Acta Crystallogr., A39 (1983) 158.
16. [16] G.M. Sheldrick, Acta Crystallogr., A46 (1990) 467.
17. [17] G.M. Sheldrick, University of Göttingen, Germany, 1993.
18. [18] K. Davies and K.C. Prout, University of Oxford, unpublished results 1993.
19. 4).