Enantioselective allylation of α-ketoester oximes with an external chiral ligand: Asymmetric synthesis of allylglycines and allylalanine

Tetrahedron Letters

Volumn 37, Issue 50, 1996, Pages 8997-9000

  Hanessian, Stephen ^a   Yang, Rui Yang ^a  

^a UNIVERSITÉ DE MONTRÉAL   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ALANINE DERIVATIVE; ALLYLGLYCINE; GLYCINE DERIVATIVE; KETONE; OXIME;

ARTICLE; CHEMICAL REACTION; DRUG SYNTHESIS; ENANTIOMER; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0030577499     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(96)02112-0     Document Type: Article

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26. 4Cl solution, extracted with EtOAc, and processed as usual. The residue was purified by chromatography on silica gel (10% EtOAc in hexanes) to afford N-benzyloxy L-allylglycine 3a (204 mg, 82%, 93%ee).
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