Enantioselective radical-chain hydrosilylation of prochiral alkenes using optically active thiol catalysts

Tetrahedron Letters

Volumn 37, Issue 50, 1996, Pages 9123-9126

  Haque, M Bodrul ^a   Roberts, Brian P ^a  

^a UNIVERSITY COLLEGE LONDON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; THIOL;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHIRALITY; DRUG SYNTHESIS; ENANTIOMER; STEREOCHEMISTRY;

EID: 0030577475     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(96)90165-3     Document Type: Article

References (17)

1. 1. Dang, H.-S.; Roberts, B.P. Tetrahedron Lett., 1995, 36, 2875.
2. 2. Alien, R.P.; Roberts, B.P.; Willis, C.R. J. Chem. Soc., Chem. Commun., 1989, 1387. Kirwan, J.N.; Roberts, B.P.; Willis, C.R. Tetrahedron Lett., 1990, 31, 5093. Dang, H.-S.; Roberts, B.P. Tetrahedron Lett., 1995, 36, 3731.
3. 2. Alien, R.P.; Roberts, B.P.; Willis, C.R. J. Chem. Soc., Chem. Commun., 1989, 1387. Kirwan, J.N.; Roberts, B.P.; Willis, C.R. Tetrahedron Lett., 1990, 31, 5093. Dang, H.-S.; Roberts, B.P. Tetrahedron Lett., 1995, 36, 3731.
4. 2. Alien, R.P.; Roberts, B.P.; Willis, C.R. J. Chem. Soc., Chem. Commun., 1989, 1387. Kirwan, J.N.; Roberts, B.P.; Willis, C.R. Tetrahedron Lett., 1990, 31, 5093. Dang, H.-S.; Roberts, B.P. Tetrahedron Lett., 1995, 36, 3731.
5. 3. Cole, S.J.; Kirwan, J.N.; Roberts, B.P.; Willis, C.R. J. Chem. Soc., Perkin Trans. 1, 1991, 103.
6. 4. Kiefer, H.; Traylor, T.G. Tetrahedron Lett., 1966, 6163. Mendenhall, G.D. Tetrahedron Lett.. 1983, 24, 451.
7. 4. Kiefer, H.; Traylor, T.G. Tetrahedron Lett., 1966, 6163. Mendenhall, G.D. Tetrahedron Lett.. 1983, 24, 451.
8. 25SH as obtained from the Aldrich Chemical Company.
9. 6. Satisfactory spectroscopic and microanalytical data were obtained for all new compounds.
10. 7. Levina, R.Ya.; Shusherina, N.P.; Lurye, M.Yu.; Orlova, N.D. Dokl. Chem. (Engl. trans.), 1956, 106, 51.
11. 10
12. 9. Rollin, P. Synth. Commun., 1986, 16, 611; Tetrahedron Lett., 1986, 27, 4169.
13. 9. Rollin, P. Synth. Commun., 1986, 16, 611; Tetrahedron Lett., 1986, 27, 4169.
14. 10. Aggarwal, V.K.; Kalomiri, M.; Thomas, A.P. Tetrahedron Asymmetry, 1994, 5, 723.
15. 11. Lee, D.-S.; Hung, S.-M.; Lai, M.-C; Chu, H.-Y.; Yang, T.-K. Org. Prep. Proced. Int., 1993, 25, 673.
16. C: 15.0, 19.3, 26.6, 27.4. 33.1, 34.0, 84.6, 127.8, 129.5, 134.5, 135.9 and 170.0.
17. 13. Roberts, B.P. J. Chem. Soc., Perkin Trans. 2, in the press.