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Volumn 520, Issue 1-2, 1996, Pages 195-200

Highly selective olefin epoxidation with manganese triazacyclononane complexes: Impact of ligand substitution

Author keywords

Epoxidation; Functionalized triazacyclononane; Hydrogen peroxide; Manganese; Solvent effects; Stereoselectivity

Indexed keywords


EID: 0030576367     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(96)06310-3     Document Type: Article
Times cited : (97)

References (36)
  • 1
    • 0024662426 scopus 로고
    • [1] For some reviews, see: (a) K.A. Jørgensen, Chem. Rev., 89 (1989) 431;
    • (1989) Chem. Rev. , vol.89 , pp. 431
    • Jørgensen, K.A.1
  • 22
    • 30144437908 scopus 로고
    • 2 mixtures show a resonance at δ = 1.33 ppm, which has previously been ascribed to 2-hydroxy-2-hydroperoxypropane [10]. There is no evidence for the formation of dimethyldioxirane in reaction conditions. Moreover, no products are formed at all when the Mn catalyst is omitted from the reaction mixture, whereas dimethyldioxirane is known to epoxidize olefins spontaneously. For NMR spectra and reactivity of dimethyldioxirane: R.W. Murray and R. Jeyaraman, J. Org. Chem., 50 (1985) 2847.
    • (1985) J. Org. Chem. , vol.50 , pp. 2847
    • Murray, R.W.1    Jeyaraman, R.2
  • 26
    • 0011492604 scopus 로고    scopus 로고
    • note
    • 3 is used as a catalyst, nor when another solvent is used.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.