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The observed spectra were fit to 50% Lorentzian and 50% Gaussian profiles, which are also the functional form used for the deconvolution of instrumental resolution in obtaining intrinsic linewidths.
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The shift due to the dynamic coupling is obtained from isotope mixture measurements. This should be distinguished from the static shift due to the interactions between permanent dipoles
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47
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Together with the dynamic coupling, the static interactions can account for the observed blue shifts in the CH stretch on C(111)-1×1 when the hydrogen coverage is reduced from a full monolayer to single adsorbate conditions
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