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Volumn 105, Issue 6, 1996, Pages 2188-2198

Electron-impact excitation of low-lying preionization-edge n→σ* and Rydberg transitions of CHF2Cl and CHFCl2: Absolute generalized oscillator strength measurement

Author keywords

[No Author keywords available]

Indexed keywords

CALCULATIONS; CHEMICAL BONDS; COMPUTER SIMULATION; DISSOCIATION; ELECTRON BEAMS; ELECTRON ENERGY LEVELS; ELECTRON TRANSITIONS; ELECTRONIC PROPERTIES; ENERGY DISSIPATION; FLUOROCARBONS; FUNCTIONS;

EID: 0030575515     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.472092     Document Type: Article
Times cited : (14)

References (45)
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    • D. A. Swick, Rev. Sci. Instrum. 31, 525 (1960); J. Karle, J. Chem. Phys. 35, 963 (1961); F. H. Read and G. L. Whiterod, Proc. Phys. Soc. (London) 85, 71 (1965); K. J. Miller, S. R. Mielczarek, and M. Krauss, J. Chem. Phys. 51, 26 (1969); M. Krauss and S. R. Mielczarek, ibid. 51, 5241 (1969); S. R. Mielczarek and K. J. Miller, Chem. Phys. Lett. 10, 369 (1971); T. C. Wong, J. S. Lee, and R. A. Bonham, Phys. Rev. A 11, 1963 (1975); H. M. Boechat Roberty and G. G. B. de Souza, J. Phys. B 25, 4641 (1992).
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    • Karle, J.1
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    • London
    • D. A. Swick, Rev. Sci. Instrum. 31, 525 (1960); J. Karle, J. Chem. Phys. 35, 963 (1961); F. H. Read and G. L. Whiterod, Proc. Phys. Soc. (London) 85, 71 (1965); K. J. Miller, S. R. Mielczarek, and M. Krauss, J. Chem. Phys. 51, 26 (1969); M. Krauss and S. R. Mielczarek, ibid. 51, 5241 (1969); S. R. Mielczarek and K. J. Miller, Chem. Phys. Lett. 10, 369 (1971); T. C. Wong, J. S. Lee, and R. A. Bonham, Phys. Rev. A 11, 1963 (1975); H. M. Boechat Roberty and G. G. B. de Souza, J. Phys. B 25, 4641 (1992).
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    • Read, F.H.1    Whiterod, G.L.2
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    • D. A. Swick, Rev. Sci. Instrum. 31, 525 (1960); J. Karle, J. Chem. Phys. 35, 963 (1961); F. H. Read and G. L. Whiterod, Proc. Phys. Soc. (London) 85, 71 (1965); K. J. Miller, S. R. Mielczarek, and M. Krauss, J. Chem. Phys. 51, 26 (1969); M. Krauss and S. R. Mielczarek, ibid. 51, 5241 (1969); S. R. Mielczarek and K. J. Miller, Chem. Phys. Lett. 10, 369 (1971); T. C. Wong, J. S. Lee, and R. A. Bonham, Phys. Rev. A 11, 1963 (1975); H. M. Boechat Roberty and G. G. B. de Souza, J. Phys. B 25, 4641 (1992).
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    • D. A. Swick, Rev. Sci. Instrum. 31, 525 (1960); J. Karle, J. Chem. Phys. 35, 963 (1961); F. H. Read and G. L. Whiterod, Proc. Phys. Soc. (London) 85, 71 (1965); K. J. Miller, S. R. Mielczarek, and M. Krauss, J. Chem. Phys. 51, 26 (1969); M. Krauss and S. R. Mielczarek, ibid. 51, 5241 (1969); S. R. Mielczarek and K. J. Miller, Chem. Phys. Lett. 10, 369 (1971); T. C. Wong, J. S. Lee, and R. A. Bonham, Phys. Rev. A 11, 1963 (1975); H. M. Boechat Roberty and G. G. B. de Souza, J. Phys. B 25, 4641 (1992).
    • (1969) J. Chem. Phys. , vol.51 , pp. 5241
    • Krauss, M.1    Mielczarek, S.R.2
  • 19
    • 5344219818 scopus 로고
    • D. A. Swick, Rev. Sci. Instrum. 31, 525 (1960); J. Karle, J. Chem. Phys. 35, 963 (1961); F. H. Read and G. L. Whiterod, Proc. Phys. Soc. (London) 85, 71 (1965); K. J. Miller, S. R. Mielczarek, and M. Krauss, J. Chem. Phys. 51, 26 (1969); M. Krauss and S. R. Mielczarek, ibid. 51, 5241 (1969); S. R. Mielczarek and K. J. Miller, Chem. Phys. Lett. 10, 369 (1971); T. C. Wong, J. S. Lee, and R. A. Bonham, Phys. Rev. A 11, 1963 (1975); H. M. Boechat Roberty and G. G. B. de Souza, J. Phys. B 25, 4641 (1992).
    • (1971) Chem. Phys. Lett. , vol.10 , pp. 369
    • Mielczarek, S.R.1    Miller, K.J.2
  • 20
    • 0000421772 scopus 로고
    • D. A. Swick, Rev. Sci. Instrum. 31, 525 (1960); J. Karle, J. Chem. Phys. 35, 963 (1961); F. H. Read and G. L. Whiterod, Proc. Phys. Soc. (London) 85, 71 (1965); K. J. Miller, S. R. Mielczarek, and M. Krauss, J. Chem. Phys. 51, 26 (1969); M. Krauss and S. R. Mielczarek, ibid. 51, 5241 (1969); S. R. Mielczarek and K. J. Miller, Chem. Phys. Lett. 10, 369 (1971); T. C. Wong, J. S. Lee, and R. A. Bonham, Phys. Rev. A 11, 1963 (1975); H. M. Boechat Roberty and G. G. B. de Souza, J. Phys. B 25, 4641 (1992).
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    • Wong, T.C.1    Lee, J.S.2    Bonham, R.A.3
  • 21
    • 5344268335 scopus 로고
    • D. A. Swick, Rev. Sci. Instrum. 31, 525 (1960); J. Karle, J. Chem. Phys. 35, 963 (1961); F. H. Read and G. L. Whiterod, Proc. Phys. Soc. (London) 85, 71 (1965); K. J. Miller, S. R. Mielczarek, and M. Krauss, J. Chem. Phys. 51, 26 (1969); M. Krauss and S. R. Mielczarek, ibid. 51, 5241 (1969); S. R. Mielczarek and K. J. Miller, Chem. Phys. Lett. 10, 369 (1971); T. C. Wong, J. S. Lee, and R. A. Bonham, Phys. Rev. A 11, 1963 (1975); H. M. Boechat Roberty and G. G. B. de Souza, J. Phys. B 25, 4641 (1992).
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    • Boechat Roberty, H.M.1    De Souza, G.G.B.2
  • 35
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    • In the present work, the error due to the variation of the effective path length or scattering volume as a function of the scattering angle is found to be considerably smaller than the errors arising from other sources, as long as the scattering angle is sufficiently far from 0°. However, if we were to extend our present measurement to below 1°, these corrections become significant and should be made using the methods given by Bonham and Wellenstein [Appl. Phys. 44, 2631 (1973)] or by Brinkmann and Trajmar [J. Phys. E 14, 245 (1981)].
    • (1973) Appl. Phys. , vol.44 , pp. 2631
    • Bonham1    Wellenstein2
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    • In the present work, the error due to the variation of the effective path length or scattering volume as a function of the scattering angle is found to be considerably smaller than the errors arising from other sources, as long as the scattering angle is sufficiently far from 0°. However, if we were to extend our present measurement to below 1°, these corrections become significant and should be made using the methods given by Bonham and Wellenstein [Appl. Phys. 44, 2631 (1973)] or by Brinkmann and Trajmar [J. Phys. E 14, 245 (1981)].
    • (1981) J. Phys. E , vol.14 , pp. 245
    • Brinkmann1    Trajmar2
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    • note
    • Although the momentum transfer is not constant over the entire energy loss range in a typical EELS spectrum recorded at a fixed scattering angle, the variation of the momentum transfer with respect to the energy loss is found to be insignificant if a sufficiently high impact energy is used. For the present experimental angular range (1°-9.5°), the corresponding momentum transfer is found to be effectively constant over the energy loss range covering the valence-shell region (0-60 eV) at 2.5 keV impact energy. The momentum transfer diverges quite notably from that at zero energy loss at higher energy loss but remains within the range expected from the angular uncertainty.
  • 42
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    • E. N. Lassettre, J. Chem. Phys. 43, 4479 (1965); M. A. Dillon and E. N. Lassettre, ibid. 62, 2373 (1975).
    • (1965) J. Chem. Phys. , vol.43 , pp. 4479
    • Lassettre, E.N.1


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