Ring-nitrosation of a secondary aromatic amine, 1,3,5-tris (phenylamino)benzene

Tetrahedron Letters

Volumn 37, Issue 28, 1996, Pages 4881-4882

  Jin, Dingyi ^a   Mendenhall, G David ^a  

^a MICHIGAN TECHNOLOGICAL UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC AMINE; NITROUS ACID; SODIUM NITRITE;

ARTICLE; CRYSTALLIZATION; NITROSATION; PROTON NUCLEAR MAGNETIC RESONANCE; X RAY CRYSTALLOGRAPHY;

EID: 0030575410     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(96)01000-3     Document Type: Article

References (7)

1. 1. Review: Williams, D.; Lyn, H. Advances in Physical Organic Chemistry 1983, 19, 381-428.
2. 2 Smith, P.A.S.; Loeppky, R.N. J. Amer. Chem. Soc. 1967, 89, 1147-1157.
3. 3. Minunni, G. Gazzetta chimica Italiana, 1891, 20, 322-356.
4. 4O: C, 75.78%; H, 5.26%; N, 14.73%. Found: C, 75.54%; H, 5.44%; N, 14.47%.
5. 5. TPAB (3.5g, 10mmol) and isopentyl nitrite (3.5g, 30mmol) in toluene (100mL) at 23°C for 15h gave a 90% yield of 1 in two crops.
6. 6. Fischer-Hepp rearrangement: March, J. "Advanced Organic Chemistry" John Wiley & Sons, NY, 4th ed, 1992, p. 558.
7. 7. Professor Nigam Rath, Chemistry Department, University of Missouri, private communication.