Examination of reactivity of protonated and deprotonated 2,5-dimercapto-1,3,4-thiadiazole and its derivatives by electrochemical experiment and semiempirical MO calculation

Journal of Electroanalytical Chemistry

Volumn 417, Issue 1-2, 1996, Pages 17-24

  Shouji, Eiichi ^a   Matsui, Hiroshi ^a   Oyama, Noboru ^a  

^a TOKYO UNIVERSITY OF AGRICULTURE AND TECHNOLOGY   (Japan)

Author keywords

Deprotonation; Mercapto thiadiazoles; Molecular orbital calculations; Protonation; Reactivity; Structure

Indexed keywords

ACETONITRILE; CHEMICAL BONDS; COMPUTATIONAL METHODS; DERIVATIVES; ELECTROCHEMISTRY; MOLECULAR STRUCTURE; ORGANIC ACIDS; PROTONS; REDOX REACTIONS; SOLUTIONS;

DEPROTONATION; HIGHEST OCCUPIED MOLECULAR ORBITALS (HOMO); MERCAPTO THIADIAZOLES; PROTONATION;

SULFUR COMPOUNDS;

EID: 0030574130     PISSN: 15726657     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-0728(96)04757-2     Document Type: Article

References (12)

1. M. Liu, S.J. Visco and L.C. De Jonghe, J. Electrochem. Soc., 136 (1989) 2570.
2. N. Oyama, T. Tatsuma, T. Sato and T. Sotomura, Nature, 373 (1995) 598.
3. T. Sotomura, H. Uemachi, Y. Miyamoto, A. Kaminaga and N. Oyama, Denki Kagaku, 61 (1993) 1366.
4. T. Sotomura, H. Uemachi, K. Takeyama, K. Naoi and N. Oyama, Electrochim. Acta, 37 (1992) 1851.
5. A. Kaminaga, T. Tatsuma, T. Sotomura and N. Oyama, J. Electrochem. Soc., 142 (1995) 47.
6. K. Naoi, Y. Oura, Y. Iwamizu and N. Oyama, J. Electrochem. Soc., 142 (1995) 354.
7. E.M. Genies and S. Picart, Synth. Met., 69 (1994) 165.
8. M. Liu, S.J. Visco and L.C. De Jonghe, J. Electrochem. Soc., 137 (1990) 750.
9. J.J.P. Stewart, J. Comput. Chem., 10 (1989) 209.
10. B. Stanovnik and M. Tišler, Croat. Chem. Acta, 37 (1965) 17.
11. J.W. Bats, Acta Crystallogr. Sect. B:, 32 (1976) 2866.
12. T. Tatsuma, T. Sotomura, T. Sato, D.A. Buttry, N. Oyama, J. Electrochem. Soc., 142 (1995) L182.