Synthesis and structure of ruthenium(II)-diene complexes

Journal of Organometallic Chemistry

Volumn 522, Issue 1, 1996, Pages 1-7

  Meléndez, Enrique ^a   Ilarraza, Raimundo ^a   Yap, Glenn P A ^b   Rheingold, Arnold L ^b  

^a INTER AMERICAN UNIVERSITY OF PUERTO RICO   (Puerto Rico)

^b UNIVERSITY OF DELAWARE   (United States)

Author keywords

Diene complexes; Ruthenium; Trans Diene coordination

Indexed keywords

EID: 0030572582     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(96)06278-X     Document Type: Article

References (24)

1. [1] J.R. Collman, L.S. Hegedus, J.R. Norton and R.G. Finke, (Eds.), Principles and Applications of Organotransition Metal Chemistry, University Science Books, Mill Valley, CA, 1987.
2. [2] G. Erker, J. Wicher, K. Engel, F. Rosenfelt, W. Dietrich and C. Kruger, J. Am. Chem. Soc., 102 (1980) 6344.
3. [3] (a) Y. Kai, N. Kanehisa, K. Miki, N. Kasai, K. Mashima, K. Nagasuna, H. Yasuda and A. Nakamura, J. Chem. Soc. Chem. Commun. (1982) 191.
4. (b) A.D. Hunter, P. Legzdins, C.R. Nurse, F.W.B. Einstein and A.C. Willis, J. Am. Chem. Soc., 107 (1985) 1791.
5. (c) E. Meléndez, A.M. Arif, A.L. Rheingold and R.D. Ernst, J. Am. Chem. Soc., 110 (1988) 8703.
6. (d) R.D. Ernst, E. Meléndez, L. Stahl and M.L. Ziegler, Organometallics, 10 (1991) 3635.
7. 4-trans-diene coordination but their structure have been elucidated using NMR spectroscopic data and not on X-ray diffraction studies [4b-e].
8. (b) T. Okamoto, H. Yasuda, A. Nakamura, Y. Kai, N. Kanehisa and N. Kasai, J. Am. Chem. Soc., 110 (1988) 5008.
9. (c) S.A. Benyunes, J.P. Day, M. Green, A.W. Al-Saadoon and T.L. Waring, Angew. Chem. Int. Ed. Engl., 29 (1990) 1416.
10. (d) S.A. Benyunes, M. Green and M.J. Grimshire, Organometallics, 8 (1989) 2268.
11. (e) P.J. Fagan, W.S. Mahoney, J.C. Calabrese and T.D. Williams, Organometallics, 9 (1990) 1843.
12. [5] (a) G. Erker, C. Krüger and G. Müller, Adv. Organomet. Chem., 24 (1985) 1.
13. (b) H. Yasuda, A. Nakamura, Angew. Chem. Int. Ed. Engl., 26 (1987) 723.
14. [6] A. Johnson and G.W. Everett, Jr., J. Am. Chem. Soc., 94 (1972) 1419.
15. [7] (a) C. Potvin and G. Pannetier, J. Less-Common Met., 22 (1970) 91.
16. (b) C. Potvin, J.M. Manoli, A. Dereigne, G. Pannetier, J. Less-Common Met., 25 (1971) 373.
17. (c) P. Powell, J. Organomet. Chem., 65 (1974) 89.
18. [8] J. Müller, K. Qiao, M. Siewing and B. Westphal, J. Organomet. Chem., 458 (1993) 219.
19. 4-2,3-dimethyl-1,3-butadiene)Cl [4e] species.
20. [10] A.D. Hunter, P. Legzdins, F.W.B. Einstein, A.C. Willis, B.E. Burten and M.G. Gatter, J. Am. Chem. Soc., 108 (1986) 3843.
21. 6, ambient): 6.51 (d, 1H, J = 9 Hz), 5.39 (s, 1H), 5.38 (s, 1H), 3.61 (s, 1H), 3.47 (d, 1H, J = 9 Hz), 3.26 (s, 3H), 2.89 (s, 1H), 2.00 (s, 3H), 1.98 (s, 3H), 1.74 (s, 3H), 1.71 (s, 3H), 0.16 (s, 9H).
22. [12] (a) S. Danishefsky, N. Kato, D. Askin and J.F. Kerwin, Jr., J. Am. Chem. Soc., 104 (1982) 358.
23. (b) S. Danishefsky, M. Hirama, K. Gombatz, T. Harayama, E. Berman and P. Schuda, J. Am. Chem. Soc., 100 (1978) 6536.
24. (c) R. Boeckman, Jr., T.M. Dolak and K.O. Culos, J. Am. Chem. Soc., 100 (1978) 7098.