Cation radical polymerization. A fundamentally new polymerization mechanism

Macromolecules

Volumn 29, Issue 10, 1996, Pages 3661-3662

  Bauld, Nathan L ^a   Aplin, J Todd ^a   Yueh, Wang ^a   Sarker, Haripada ^a   Bellville, Dennis J ^b  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

^b Hoechst Celanese Corporation   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; ADDITION REACTIONS; CATALYSTS; CHROMATOGRAPHY; ELECTROPOLYMERIZATION; MOLECULAR WEIGHT; MOLECULES; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC POLYMERS; PHOTOSYNTHESIS; SALTS;

ALUMINA CHROMATOGRAPHY; CATION RADICAL POLYMERIZATION; CYCLOADDITIONS; ELECTRON TRANSFER;

CATIONIC POLYMERIZATION;

EID: 0030572116     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma951694c     Document Type: Article

References (8)

1. Bauld, N. L. Tetrahedron 1989, 45, 5307-5363.
2. Bauld, N. L. Advances in Electron Transfer Chemistry; Mariano, P. S., Ed.; JAI Press: Greenwich, 1992; Vol. 2. pp 1-66.
3. Bauld, N. L.; Pabon, R. J. Am. Chem. Soc. 1983, 105, 633-634.
4. Lewis, F. D.; Kojima, M. J. Am. Chem. Soc. 1988, 110, 8864-8670.
5. 13C NMR absorptions occur at δ 18.9, 43.3, 52.7, 55.2, 113.8, 127.8, 136.0, and 158.1.
6. 3, 517 The width of the molecular weight distribution was measured by the half peak height. We wish to thank Professors Stephen Webber and Grant Willson for the use of their equipment and Drs. Cao Ti and Qin Anwei for their assistance in making these measurements.
7. + reference electrode was used. A lithium perchlorate electrolyte was dissolved in a 1:3 acetonitrile:methylene chloride solvent mixure. Electrolysis was carried ont at 1.06V vs SCE, the oxidation potential of 1.
8. Gassman, P. G.; Singleton, D. A. J. Am. Chem. Soc. 1984, 106, 7993-7994.