On the mechanism of carbonylation in acetic acid and higher acid synthesis from methanol and syngas mixtures on supported rhodium catalysts

Journal of Molecular Catalysis A: Chemical

Volumn 107, Issue 1-3, 1996, Pages 367-378

  Chateau, L ^a   Hindermann, J P ^a   Kiennemann, A ^a   Tempesti, E ^b  

^a CNRS   (France)

^b UNIVERSITY OF BRESCIA   (Italy)

Author keywords

Acetic acid; Carbonylation; Carboxylic acids; Mechanism; Methanol; Rhodium catalysts

Indexed keywords

ACETIC ACID; CARBON MONOXIDE; CARBONYLATION; CARBOXYLIC ACIDS; CATALYST SUPPORTS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; ISOMERIZATION; METHANOL; MIXTURES; RHODIUM; SYNTHESIS (CHEMICAL); SYNTHESIS GAS;

CHEMICAL TRAPPING; METHYL FORMATE; METHYL IODIDE;

CATALYSTS;

EID: 0030572036     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/1381-1169(95)00176-X     Document Type: Article

References (41)

1. R. Schultz, (Monsanto Co.), US Pat. 3 717 670 (1973).
2. J.F. Knifton, Prep. Am. Chem. Soc. Div. Pet. Chem., 31 (1986) 26.
3. U. Dettmeier, E.I. Leupold, H. Poell, H.J. Schmidt and J. Schultz, Erdöl Kohle, Erdgas, Petrochem., 38 (1985) 59.
4. T.W. Dekleva and D. Forster, Adv. Catal., 34 (1986) 81.
5. M. Roeper, E.O. Elvevoll and M. Luetgendorf, Erdöl Kohle, Erdgas, Petrochem., 38 (1985) 38.
6. Halcon CD Group Inc., Neth. Pat. Appl. NL 8202 188 (1982).
7. D.J.M. Ray (BP Chemicals Ltd.), Eur. Pat. Appl. EP 60 695 (1982).
8. Agency Industrial Sciences and Technology. Jpn. Pat. JP 5,931,730 (1984).
9. E. Tempesti, A. Kiennemann, S. Rapagna, G. Jenner, L. Giurffre and C. Mazzocchia. It. Pat. IT 207 456 (1989).
10. E. Tempesti. A. Kiennemann, S. Rapagna, C. Mazzocchia and L. Giuffre, Chem. Ind., (1991) 548.
11. J. Lamotte, Thèse d'Etat, Caen, (1987).
12. R. Breault, J.P. Hindermann, A. Kiennemann and M. Laurin, Stud. Surf. Sci. Catal., 19 (1984) 489.
13. A.M. de Jong and J.W. Niemantsverdriet, J. Chem. Phys., 101 (1994) 10126.
14. J.C. Lavalley, J. Saussey, J. Lamotte, R. Breault, J.P. Hindermann and A. Kiennemann, J. Phys. Chem., 94 (1990) 5941.
15. D. Demri, J.P. Hindermann, A. Kiennemann and C. Mazzocchia, Catal. Lett., 23 (1994) 227.
16. B.J. Kip and E.G.F. Hermans, in M.J. Philipps and M. Ternan (Eds.), Proc. 9th Int. Congr. Catal. (Calgary), Vol. II, 1988, p. 821.
17. J.P. Hindermann, G.J. Hutchings and A. Kiennemann, Catal. Rev. Sci. Eng., 35 (1993) 1 and refs. therein.
18. H.J.F. van't Blik, J.B.D.A. van Zon,T. Huizinga,J.C. Vis,D.C. Koningsberger and R. Prins, J. Am. Chem. Soc. 107 (1985) 3139.
19. F. Solymosi and M. Pasztor, J. Phys. Chem., 89 (1985) 4789.
20. J.T. Yates, Jr., T.M. Duncan, S.D. Worley and R.W. Vaughan, J. Chem. Phys., 70 (1979) 1219.
21. H.J.F. van't Blik, J.B.D.A. van Zon, D.C. Koningsberger and R. Prins, J. Mol. Catal., 25 (1984) 379.
22. F. Solymosi and M. Pasztor, J. Phys. Chem. 90 (1986) 5312.
23. F. Solymosi and H. Knözinger, J. Chem. Soc. Faraday Trans 86 (1990) 389.
24. M. Ichikawa, P.E. Hoffmann and A. Fukuoka, J. Chem. Soc. Chem. Commun., (1985) 1395.
25. D. Demri, L. Chateau, J.P. Hindermann, A. Kiennemann and M.M. Bettahar, J. Mol. Catal. A, in press.
26. G.J. Millar, C.H. Rochester and K.C. Waugh, J. Chem. Soc., Faraday Trans, 87 (1991) 1491.
27. C. Li, K. Domen, K.I. Maruya and T. Onishi, J. Catal., 125 (1990) 445.
28. G. Busca, J. Lamotte, J.C. Lavalley and V. Lorenzelli, J. Am. Chem. Soc., 109 (1987) 5197.
29. J. Saussey, T. Rais and J.C. Lavalley, Bull. Soc. Chim. Fr., (1985) 305.
30. H. Hattori and G.W. Wang, Proc. 8th Int. Congr. Catal. (Berlin), Vol. III, Verlag Chemie, Weinheim, 1984, p. 219.
31. B.A. Sexton, Chem. Phys. Lett., 65 (1979) 469.
32. K. Ito and H.J. Bernstein, Can. J. Chem., 34 (1956) 170.
33. D. Demri, J.P. Hindermann, C. Diagne and A. Kiennemann, J. Chem. Soc., Faraday Trans. 1, 90 (1994) 501.
34. M.A. Henderson, Y. Zhou and J.M. White, J. Am. Chem. Soc., 111 (1989) 1185.
35. W. Hieber, G. Braun and W. Beck, Chem. Ber., 93 (1960) 901.
36. C. Binet, A. Jadi and J.C. Lavalley, J. Chim. Phys., 89 (1992) 1441.
37. F. Solymosi, A. Berko and T.I. Tarnoczi, Surf. Sci., 141 (1984) 553.
38. M. Ichikawa and T. Fukushima, J. Chem. Soc., Chem. Commun., (1985) 321.
39. N. Yu Kositsyna and I.I. Moiseev, Kinet. Catal. 32 (1991) 985.
40. T. Onishi, T. Suzuki, T. Yamakawa and S. Shinoda, J. Mol. Catal., 84 (1993) 51.
41. D. Forster, Adv. Organomet. Chem., 17 (1979) 255.