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2] via a route similar to the one outlined for 1a were reported while this paper was in print. They lead to a monomeric Rh(I) formate complex that was shown by X-ray diffraction to contain a κO-bound formate unit: V.V. Grushin, V.F. Kuznetsov, C. Bensimon and H. Alper, Organometallics, 14 (1995) 3927.
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-1 can be predicted for a μi-κO-bound formate by extrapolation of the data from Ref. [14]
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-1 can be predicted for a μi-κO-bound formate by extrapolation of the data from Ref. [14].
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