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Volumn 52, Issue 45, 1996, Pages 14341-14348

Arene-catalysed lithiation of triflates and triflamides under Barbier-type conditions: An indirect transformation of alcohols and amines into organolithium compounds

Author keywords

[No Author keywords available]

Indexed keywords

ALKANOL;

EID: 0030569283     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4020(96)00886-1     Document Type: Article
Times cited : (19)

References (42)
  • 1
  • 2
    • 0012008861 scopus 로고
    • Schlosser, M., Ed.; J. Wiley & Sons: Chichester
    • 2. (a) Schlosser, M. In Organometallics in Syntheses; Schlosser, M., Ed.; J. Wiley & Sons: Chichester, 1994; pp. 47-50.
    • (1994) Organometallics in Syntheses , pp. 47-50
    • Schlosser, M.1
  • 3
    • 0003491442 scopus 로고
    • Band 13/I; G. Thieme Verlag: Stuttgart
    • (b) Schölkopff, U. In Houben-Weyl, Methoden der Organischen Chemie, Band 13/I; G. Thieme Verlag: Stuttgart, 1970; pp. 127-133. (c) Ref. 1, pp. 47-49. (d) Shapiro, R. H. Org. React. 1976, 23, 405-507.
    • (1970) Houben-Weyl, Methoden der Organischen Chemie , pp. 127-133
    • Schölkopff, U.1
  • 4
    • 0011955273 scopus 로고    scopus 로고
    • Ref. 1, pp. 47-49
    • (c) Ref. 1, pp. 47-49.
  • 9
    • 0029097618 scopus 로고
    • 5. For another methodology based on arene-catalysed lithiation reactions of allylic and benzylic alcohols or their silylated derivatives, see: Alonso, E.; Guijarro, D.; Yus, M. Tetrahedron 1995, 51, 11457-11464.
    • (1995) Tetrahedron , vol.51 , pp. 11457-11464
    • Alonso, E.1    Guijarro, D.2    Yus, M.3
  • 14
    • 0030605835 scopus 로고    scopus 로고
    • 8. For the last paper from our laboratory on the use of the arene-catalysed lithiation, see: Guijarro, A.; Ortiz, J.; Yus, M. Tetrahedron Lett. 1996, 37, 5597-5600.
    • (1996) Tetrahedron Lett. , vol.37 , pp. 5597-5600
    • Guijarro, A.1    Ortiz, J.2    Yus, M.3
  • 23
    • 85136556023 scopus 로고    scopus 로고
    • 3 (1.2 mmol) was added to the reaction mixture before the addition of this reagent and benzaldehyde, and the temperature was allowed to rise to 20°C before the final hydrolyses
    • 3 (1.2 mmol) was added to the reaction mixture before the addition of this reagent and benzaldehyde, and the temperature was allowed to rise to 20°C before the final hydrolyses.


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