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Volumn 513, Issue 1-2, 1996, Pages 163-172

The decomposition reaction of the dialane radical anion [R2 Al-̇AlR2]- in DME(II): Crystal structures of the aluminium glycolates [R2Al(OCH2)2]K(DME) and R2Al(OCH2)2Al(R)(OCH2)2AlR2 (R = CH(SiMe3)2)

Author keywords

Aluminium aluminium bond; Glycolate; Potassium; Radical

Indexed keywords


EID: 0030567442     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(95)05932-F     Document Type: Article
Times cited : (31)

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    • [17] Some recent results: P.L. Gurian, L.K. Cheatham, J.W. Ziller and A.R. Barron, J. Chem. Soc., Dalton Trans., (1991) 1449; J.L. Atwood, S.G. Bott, S. Harvey and P.C. Junk, Organometallics, 13 (1994) 4151; J. Lewinski, J. Zachara, B. Mank and S. Pasynkiewicz, J. Organomet. Chem., 454 (1993) 5; J.L. Atwood, F.C. Lee, C.L. Raston and K.D. Robinson, J. Chem. Soc., Dalton Trans., (1994) 2019; M.F. Self, W.T. Pennington, J.A. Laske and G.H. Robinson, Organometallics, 10 (1991) 36; A.D. Pajerski, T.P. Cleary, M. Parvez, G.W. Gokel and H.G. Richey, Jr., Organometallics, 11 (1992) 1400; S.J. Trepanier and S. Wang, Organometallics, 13 (1994) 2213; G. Müller and J. Lachmann, Z. Naturforsch., Teil B, 48 (1993) 1544; J. Pinkas, T. Wang, R.A. Jacobson and J.G. Verkade, Inorg. Chem., 33 (1994) 4202, 33 (1994) 5244; J.T. Leman, J. Braddock-Wilking, A.J. Coolong and A.R. Barron, Inorg. Chem., 32 (1993) 4324; D.G. Hendershot, M. Barber, R. Kumar and J.P. Oliver, Organometallics, 10 (1991) 3302; J. Müller and U. Englert, Chem. Ber., 128 (1995) 493.
    • (1991) J. Chem. Soc., Dalton Trans. , pp. 1449
    • Gurian, P.L.1    Cheatham, L.K.2    Ziller, J.W.3    Barron, A.R.4
  • 47
    • 0001636531 scopus 로고
    • [17] Some recent results: P.L. Gurian, L.K. Cheatham, J.W. Ziller and A.R. Barron, J. Chem. Soc., Dalton Trans., (1991) 1449; J.L. Atwood, S.G. Bott, S. Harvey and P.C. Junk, Organometallics, 13 (1994) 4151; J. Lewinski, J. Zachara, B. Mank and S. Pasynkiewicz, J. Organomet. Chem., 454 (1993) 5; J.L. Atwood, F.C. Lee, C.L. Raston and K.D. Robinson, J. Chem. Soc., Dalton Trans., (1994) 2019; M.F. Self, W.T. Pennington, J.A. Laske and G.H. Robinson, Organometallics, 10 (1991) 36; A.D. Pajerski, T.P. Cleary, M. Parvez, G.W. Gokel and H.G. Richey, Jr., Organometallics, 11 (1992) 1400; S.J. Trepanier and S. Wang, Organometallics, 13 (1994) 2213; G. Müller and J. Lachmann, Z. Naturforsch., Teil B, 48 (1993) 1544; J. Pinkas, T. Wang, R.A. Jacobson and J.G. Verkade, Inorg. Chem., 33 (1994) 4202, 33 (1994) 5244; J.T. Leman, J. Braddock-Wilking, A.J. Coolong and A.R. Barron, Inorg. Chem., 32 (1993) 4324; D.G. Hendershot, M. Barber, R. Kumar and J.P. Oliver, Organometallics, 10 (1991) 3302; J. Müller and U. Englert, Chem. Ber., 128 (1995) 493.
    • (1994) Organometallics , vol.13 , pp. 4151
    • Atwood, J.L.1    Bott, S.G.2    Harvey, S.3    Junk, P.C.4
  • 48
    • 0001774457 scopus 로고
    • [17] Some recent results: P.L. Gurian, L.K. Cheatham, J.W. Ziller and A.R. Barron, J. Chem. Soc., Dalton Trans., (1991) 1449; J.L. Atwood, S.G. Bott, S. Harvey and P.C. Junk, Organometallics, 13 (1994) 4151; J. Lewinski, J. Zachara, B. Mank and S. Pasynkiewicz, J. Organomet. Chem., 454 (1993) 5; J.L. Atwood, F.C. Lee, C.L. Raston and K.D. Robinson, J. Chem. Soc., Dalton Trans., (1994) 2019; M.F. Self, W.T. Pennington, J.A. Laske and G.H. Robinson, Organometallics, 10 (1991) 36; A.D. Pajerski, T.P. Cleary, M. Parvez, G.W. Gokel and H.G. Richey, Jr., Organometallics, 11 (1992) 1400; S.J. Trepanier and S. Wang, Organometallics, 13 (1994) 2213; G. Müller and J. Lachmann, Z. Naturforsch., Teil B, 48 (1993) 1544; J. Pinkas, T. Wang, R.A. Jacobson and J.G. Verkade, Inorg. Chem., 33 (1994) 4202, 33 (1994) 5244; J.T. Leman, J. Braddock-Wilking, A.J. Coolong and A.R. Barron, Inorg. Chem., 32 (1993) 4324; D.G. Hendershot, M. Barber, R. Kumar and J.P. Oliver, Organometallics, 10 (1991) 3302; J. Müller and U. Englert, Chem. Ber., 128 (1995) 493.
    • (1993) J. Organomet. Chem. , vol.454 , pp. 5
    • Lewinski, J.1    Zachara, J.2    Mank, B.3    Pasynkiewicz, S.4
  • 49
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    • [17] Some recent results: P.L. Gurian, L.K. Cheatham, J.W. Ziller and A.R. Barron, J. Chem. Soc., Dalton Trans., (1991) 1449; J.L. Atwood, S.G. Bott, S. Harvey and P.C. Junk, Organometallics, 13 (1994) 4151; J. Lewinski, J. Zachara, B. Mank and S. Pasynkiewicz, J. Organomet. Chem., 454 (1993) 5; J.L. Atwood, F.C. Lee, C.L. Raston and K.D. Robinson, J. Chem. Soc., Dalton Trans., (1994) 2019; M.F. Self, W.T. Pennington, J.A. Laske and G.H. Robinson, Organometallics, 10 (1991) 36; A.D. Pajerski, T.P. Cleary, M. Parvez, G.W. Gokel and H.G. Richey, Jr., Organometallics, 11 (1992) 1400; S.J. Trepanier and S. Wang, Organometallics, 13 (1994) 2213; G. Müller and J. Lachmann, Z. Naturforsch., Teil B, 48 (1993) 1544; J. Pinkas, T. Wang, R.A. Jacobson and J.G. Verkade, Inorg. Chem., 33 (1994) 4202, 33 (1994) 5244; J.T. Leman, J. Braddock-Wilking, A.J. Coolong and A.R. Barron, Inorg. Chem., 32 (1993) 4324; D.G. Hendershot, M. Barber, R. Kumar and J.P. Oliver, Organometallics, 10 (1991) 3302; J. Müller and U. Englert, Chem. Ber., 128 (1995) 493.
    • (1994) J. Chem. Soc., Dalton Trans. , pp. 2019
    • Atwood, J.L.1    Lee, F.C.2    Raston, C.L.3    Robinson, K.D.4
  • 50
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    • [17] Some recent results: P.L. Gurian, L.K. Cheatham, J.W. Ziller and A.R. Barron, J. Chem. Soc., Dalton Trans., (1991) 1449; J.L. Atwood, S.G. Bott, S. Harvey and P.C. Junk, Organometallics, 13 (1994) 4151; J. Lewinski, J. Zachara, B. Mank and S. Pasynkiewicz, J. Organomet. Chem., 454 (1993) 5; J.L. Atwood, F.C. Lee, C.L. Raston and K.D. Robinson, J. Chem. Soc., Dalton Trans., (1994) 2019; M.F. Self, W.T. Pennington, J.A. Laske and G.H. Robinson, Organometallics, 10 (1991) 36; A.D. Pajerski, T.P. Cleary, M. Parvez, G.W. Gokel and H.G. Richey, Jr., Organometallics, 11 (1992) 1400; S.J. Trepanier and S. Wang, Organometallics, 13 (1994) 2213; G. Müller and J. Lachmann, Z. Naturforsch., Teil B, 48 (1993) 1544; J. Pinkas, T. Wang, R.A. Jacobson and J.G. Verkade, Inorg. Chem., 33 (1994) 4202, 33 (1994) 5244; J.T. Leman, J. Braddock-Wilking, A.J. Coolong and A.R. Barron, Inorg. Chem., 32 (1993) 4324; D.G. Hendershot, M. Barber, R. Kumar and J.P. Oliver, Organometallics, 10 (1991) 3302; J. Müller and U. Englert, Chem. Ber., 128 (1995) 493.
    • (1991) Organometallics , vol.10 , pp. 36
    • Self, M.F.1    Pennington, W.T.2    Laske, J.A.3    Robinson, G.H.4
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    • [17] Some recent results: P.L. Gurian, L.K. Cheatham, J.W. Ziller and A.R. Barron, J. Chem. Soc., Dalton Trans., (1991) 1449; J.L. Atwood, S.G. Bott, S. Harvey and P.C. Junk, Organometallics, 13 (1994) 4151; J. Lewinski, J. Zachara, B. Mank and S. Pasynkiewicz, J. Organomet. Chem., 454 (1993) 5; J.L. Atwood, F.C. Lee, C.L. Raston and K.D. Robinson, J. Chem. Soc., Dalton Trans., (1994) 2019; M.F. Self, W.T. Pennington, J.A. Laske and G.H. Robinson, Organometallics, 10 (1991) 36; A.D. Pajerski, T.P. Cleary, M. Parvez, G.W. Gokel and H.G. Richey, Jr., Organometallics, 11 (1992) 1400; S.J. Trepanier and S. Wang, Organometallics, 13 (1994) 2213; G. Müller and J. Lachmann, Z. Naturforsch., Teil B, 48 (1993) 1544; J. Pinkas, T. Wang, R.A. Jacobson and J.G. Verkade, Inorg. Chem., 33 (1994) 4202, 33 (1994) 5244; J.T. Leman, J. Braddock-Wilking, A.J. Coolong and A.R. Barron, Inorg. Chem., 32 (1993) 4324; D.G. Hendershot, M. Barber, R. Kumar and J.P. Oliver, Organometallics, 10 (1991) 3302; J. Müller and U. Englert, Chem. Ber., 128 (1995) 493.
    • (1992) Organometallics , vol.11 , pp. 1400
    • Pajerski, A.D.1    Cleary, T.P.2    Parvez, M.3    Gokel, G.W.4    Richey H.G., Jr.5
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    • [17] Some recent results: P.L. Gurian, L.K. Cheatham, J.W. Ziller and A.R. Barron, J. Chem. Soc., Dalton Trans., (1991) 1449; J.L. Atwood, S.G. Bott, S. Harvey and P.C. Junk, Organometallics, 13 (1994) 4151; J. Lewinski, J. Zachara, B. Mank and S. Pasynkiewicz, J. Organomet. Chem., 454 (1993) 5; J.L. Atwood, F.C. Lee, C.L. Raston and K.D. Robinson, J. Chem. Soc., Dalton Trans., (1994) 2019; M.F. Self, W.T. Pennington, J.A. Laske and G.H. Robinson, Organometallics, 10 (1991) 36; A.D. Pajerski, T.P. Cleary, M. Parvez, G.W. Gokel and H.G. Richey, Jr., Organometallics, 11 (1992) 1400; S.J. Trepanier and S. Wang, Organometallics, 13 (1994) 2213; G. Müller and J. Lachmann, Z. Naturforsch., Teil B, 48 (1993) 1544; J. Pinkas, T. Wang, R.A. Jacobson and J.G. Verkade, Inorg. Chem., 33 (1994) 4202, 33 (1994) 5244; J.T. Leman, J. Braddock-Wilking, A.J. Coolong and A.R. Barron, Inorg. Chem., 32 (1993) 4324; D.G. Hendershot, M. Barber, R. Kumar and J.P. Oliver, Organometallics, 10 (1991) 3302; J. Müller and U. Englert, Chem. Ber., 128 (1995) 493.
    • (1994) Organometallics , vol.13 , pp. 2213
    • Trepanier, S.J.1    Wang, S.2
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    • [17] Some recent results: P.L. Gurian, L.K. Cheatham, J.W. Ziller and A.R. Barron, J. Chem. Soc., Dalton Trans., (1991) 1449; J.L. Atwood, S.G. Bott, S. Harvey and P.C. Junk, Organometallics, 13 (1994) 4151; J. Lewinski, J. Zachara, B. Mank and S. Pasynkiewicz, J. Organomet. Chem., 454 (1993) 5; J.L. Atwood, F.C. Lee, C.L. Raston and K.D. Robinson, J. Chem. Soc., Dalton Trans., (1994) 2019; M.F. Self, W.T. Pennington, J.A. Laske and G.H. Robinson, Organometallics, 10 (1991) 36; A.D. Pajerski, T.P. Cleary, M. Parvez, G.W. Gokel and H.G. Richey, Jr., Organometallics, 11 (1992) 1400; S.J. Trepanier and S. Wang, Organometallics, 13 (1994) 2213; G. Müller and J. Lachmann, Z. Naturforsch., Teil B, 48 (1993) 1544; J. Pinkas, T. Wang, R.A. Jacobson and J.G. Verkade, Inorg. Chem., 33 (1994) 4202, 33 (1994) 5244; J.T. Leman, J. Braddock-Wilking, A.J. Coolong and A.R. Barron, Inorg. Chem., 32 (1993) 4324; D.G. Hendershot, M. Barber, R. Kumar and J.P. Oliver, Organometallics, 10 (1991) 3302; J. Müller and U. Englert, Chem. Ber., 128 (1995) 493.
    • (1993) Z. Naturforsch., Teil B , vol.48 , pp. 1544
    • Müller, G.1    Lachmann, J.2
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    • [17] Some recent results: P.L. Gurian, L.K. Cheatham, J.W. Ziller and A.R. Barron, J. Chem. Soc., Dalton Trans., (1991) 1449; J.L. Atwood, S.G. Bott, S. Harvey and P.C. Junk, Organometallics, 13 (1994) 4151; J. Lewinski, J. Zachara, B. Mank and S. Pasynkiewicz, J. Organomet. Chem., 454 (1993) 5; J.L. Atwood, F.C. Lee, C.L. Raston and K.D. Robinson, J. Chem. Soc., Dalton Trans., (1994) 2019; M.F. Self, W.T. Pennington, J.A. Laske and G.H. Robinson, Organometallics, 10 (1991) 36; A.D. Pajerski, T.P. Cleary, M. Parvez, G.W. Gokel and H.G. Richey, Jr., Organometallics, 11 (1992) 1400; S.J. Trepanier and S. Wang, Organometallics, 13 (1994) 2213; G. Müller and J. Lachmann, Z. Naturforsch., Teil B, 48 (1993) 1544; J. Pinkas, T. Wang, R.A. Jacobson and J.G. Verkade, Inorg. Chem., 33 (1994) 4202, 33 (1994) 5244; J.T. Leman, J. Braddock-Wilking, A.J. Coolong and A.R. Barron, Inorg. Chem., 32 (1993) 4324; D.G. Hendershot, M. Barber, R. Kumar and J.P. Oliver, Organometallics, 10 (1991) 3302; J. Müller and U. Englert, Chem. Ber., 128 (1995) 493.
    • (1994) Inorg. Chem. , vol.33 , pp. 4202
    • Pinkas, J.1    Wang, T.2    Jacobson, R.A.3    Verkade, J.G.4
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    • [17] Some recent results: P.L. Gurian, L.K. Cheatham, J.W. Ziller and A.R. Barron, J. Chem. Soc., Dalton Trans., (1991) 1449; J.L. Atwood, S.G. Bott, S. Harvey and P.C. Junk, Organometallics, 13 (1994) 4151; J. Lewinski, J. Zachara, B. Mank and S. Pasynkiewicz, J. Organomet. Chem., 454 (1993) 5; J.L. Atwood, F.C. Lee, C.L. Raston and K.D. Robinson, J. Chem. Soc., Dalton Trans., (1994) 2019; M.F. Self, W.T. Pennington, J.A. Laske and G.H. Robinson, Organometallics, 10 (1991) 36; A.D. Pajerski, T.P. Cleary, M. Parvez, G.W. Gokel and H.G. Richey, Jr., Organometallics, 11 (1992) 1400; S.J. Trepanier and S. Wang, Organometallics, 13 (1994) 2213; G. Müller and J. Lachmann, Z. Naturforsch., Teil B, 48 (1993) 1544; J. Pinkas, T. Wang, R.A. Jacobson and J.G. Verkade, Inorg. Chem., 33 (1994) 4202, 33 (1994) 5244; J.T. Leman, J. Braddock-Wilking, A.J. Coolong and A.R. Barron, Inorg. Chem., 32 (1993) 4324; D.G. Hendershot, M. Barber, R. Kumar and J.P. Oliver, Organometallics, 10 (1991) 3302; J. Müller and U. Englert, Chem. Ber., 128 (1995) 493.
    • (1994) Inorg. Chem. , vol.33 , pp. 5244
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    • [17] Some recent results: P.L. Gurian, L.K. Cheatham, J.W. Ziller and A.R. Barron, J. Chem. Soc., Dalton Trans., (1991) 1449; J.L. Atwood, S.G. Bott, S. Harvey and P.C. Junk, Organometallics, 13 (1994) 4151; J. Lewinski, J. Zachara, B. Mank and S. Pasynkiewicz, J. Organomet. Chem., 454 (1993) 5; J.L. Atwood, F.C. Lee, C.L. Raston and K.D. Robinson, J. Chem. Soc., Dalton Trans., (1994) 2019; M.F. Self, W.T. Pennington, J.A. Laske and G.H. Robinson, Organometallics, 10 (1991) 36; A.D. Pajerski, T.P. Cleary, M. Parvez, G.W. Gokel and H.G. Richey, Jr., Organometallics, 11 (1992) 1400; S.J. Trepanier and S. Wang, Organometallics, 13 (1994) 2213; G. Müller and J. Lachmann, Z. Naturforsch., Teil B, 48 (1993) 1544; J. Pinkas, T. Wang, R.A. Jacobson and J.G. Verkade, Inorg. Chem., 33 (1994) 4202, 33 (1994) 5244; J.T. Leman, J. Braddock-Wilking, A.J. Coolong and A.R. Barron, Inorg. Chem., 32 (1993) 4324; D.G. Hendershot, M. Barber, R. Kumar and J.P. Oliver, Organometallics, 10 (1991) 3302; J. Müller and U. Englert, Chem. Ber., 128 (1995) 493.
    • (1993) Inorg. Chem. , vol.32 , pp. 4324
    • Leman, J.T.1    Braddock-Wilking, J.2    Coolong, A.J.3    Barron, A.R.4
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    • [17] Some recent results: P.L. Gurian, L.K. Cheatham, J.W. Ziller and A.R. Barron, J. Chem. Soc., Dalton Trans., (1991) 1449; J.L. Atwood, S.G. Bott, S. Harvey and P.C. Junk, Organometallics, 13 (1994) 4151; J. Lewinski, J. Zachara, B. Mank and S. Pasynkiewicz, J. Organomet. Chem., 454 (1993) 5; J.L. Atwood, F.C. Lee, C.L. Raston and K.D. Robinson, J. Chem. Soc., Dalton Trans., (1994) 2019; M.F. Self, W.T. Pennington, J.A. Laske and G.H. Robinson, Organometallics, 10 (1991) 36; A.D. Pajerski, T.P. Cleary, M. Parvez, G.W. Gokel and H.G. Richey, Jr., Organometallics, 11 (1992) 1400; S.J. Trepanier and S. Wang, Organometallics, 13 (1994) 2213; G. Müller and J. Lachmann, Z. Naturforsch., Teil B, 48 (1993) 1544; J. Pinkas, T. Wang, R.A. Jacobson and J.G. Verkade, Inorg. Chem., 33 (1994) 4202, 33 (1994) 5244; J.T. Leman, J. Braddock-Wilking, A.J. Coolong and A.R. Barron, Inorg. Chem., 32 (1993) 4324; D.G. Hendershot, M. Barber, R. Kumar and J.P. Oliver, Organometallics, 10 (1991) 3302; J. Müller and U. Englert, Chem. Ber., 128 (1995) 493.
    • (1991) Organometallics , vol.10 , pp. 3302
    • Hendershot, D.G.1    Barber, M.2    Kumar, R.3    Oliver, J.P.4
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