Complete asymmetric induction in [1,2]-Wittig rearrangement of a system involving a binaphthol moiety

Tetrahedron Letters

Volumn 37, Issue 49, 1996, Pages 8903-8904

  Kiyooka, Syun Ichi ^a   Tsutsui, Takanori ^a   Kira, Tomiko ^a  

^a KOCHI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

1,1' BINAPHTHYL DERIVATIVE;

ARTICLE; DRUG SYNTHESIS; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0030566844     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(96)02080-1     Document Type: Article

References (16)

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2. 2. a) Seyden-Penne, J. Chiral Auxiliaries and Ligands in Asymmetric Synthesis, John Wiley & Sons, New York, 1995, p 172.
3. b) Tanaka, F. ; Node, M. ; Tanaka, K. ; Mizuchi, M.; Hosoi, S. ; Nakayama, M. ; Taga, T. ; Fuji, K. J. Am. Chem. Soc. 1995, 117, 12159-12171 . ; Highly stereoselective alkylation of binaphthyl phenylacetate was studied.
4. 3. Heathcock, C. H. ; Kiyooka, S. -i. unpublished results in the postdoctral research works (S. -i. K.) at Berkeley, 1982 ; The lithium enolates prepared from the acetate and propionate rapidly decomposed before the following aldol condensation.
5. 3) ; 2a δ 56.08, 72.98, 96.12, 117.73, 123.71, 124.66, 125.51, 125.84, 126.06, 126.15, 126.67, 127.83, 127.95, 128.65, 130.02, 130.08, 132.10, 132.80, 132.98, 134.17, 141.09, 142.78, 152.34. 2d δ 55.81, 71.73, 96.06, 114.08, 117.98, 123.65, 124.50, 124.75, 125.75, 126.06, 126.24, 125.52, 127.80, 128.50, 129.87, 131.67, 132.77, 132.95, 134.08, 138.83, 139.47, 152.19.
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