A model of the oxidation of iron and cadmium sulfide in sediments

Environmental Toxicology and Chemistry

Volumn 15, Issue 12, 1996, Pages 2168-2186

  Di Toro, Dominic M ^a,b   Mahony, John D ^a   Hansen, David J ^c   Berry, Walter J ^c  

^a MANHATTAN COLLEGE   (United States)

^b HydroQual Inc   (United States)

^c U S ENVIRONMENTAL PROTECTION AGENCY   (United States)

Author keywords

Model; Seasonal variation; Sediment quality criteria

Indexed keywords

CADMIUM COMPOUNDS; CARBON; HAZARDOUS MATERIALS; IRON; MATHEMATICAL MODELS; MIXING; PARTICLES (PARTICULATE MATTER); SEDIMENTS; TOXICITY; TRANSPORT PROPERTIES;

ACID VOLATILE SULFIDE; CADMIUM SULFIDE; PARTICULATE ORGANIC CARBON; SEASONAL VARIATION; SEDIMENT QUALITY CRITERIA; SIMULTANEOUSLY EXTRACTED CADMIUM;

OXIDATION;

CADMIUM SULFIDE; IRON;

ARTICLE; OXIDATION; PRIORITY JOURNAL; SEASONAL VARIATION; SEDIMENT; SOIL POLLUTION;

EID: 0030561348     PISSN: 07307268     EISSN: None     Source Type: Journal    
DOI: 10.1002/etc.5620151212     Document Type: Article

References (35)

1. Di Toro, D.M., J.D. Mahony, D.J. Hansen, K.J. Scott, M.B. Hicks, S.M. Mayr and M.S. Redmond. 1990. Toxicity of cadmium in sediments: The role of acid-volatile sulfide. Environ. Toxicol. Chem. 9:1487-1502.
2. Di Toro, D.M., J.D. Mahony, D.J. Hansen, K.J. Scott, A.R. Carlson and G.T. Ankley. 1991. Acid volatile sulfide predicts the acute toxicity of cadmium and nickel in sediments. Environ. Sci. Technol. 26:96-101.
3. Hansen, D.J., J.D. Mahony, W.J. Berry, S.J. Benyi, J.M. Corbin, S.D. Pratt, D.M. Di Toro and M.B. Able. 1996. Chronic effect of cadmium in sediments on colonization by benthic marine organisms: An evaluation of the role of interstitial cadmium and acid-volatile sulfide in biological availability. Environ. Toxicol. Chem. 15:2126-2137.
4. Berry, W.J., D.J. Hansen, J.D. Mahony, D.L. Robson, D.M. Di Toro, B.P. Shipley, B. Rogers, J.M. Corbin and W.S. Boothman. 1996. Predicting the toxicity of metal-spiked laboratory sediments using acid-volatile sulfide and interstitial water normalizations. Environ. Toxicol. Chem. 15:2067-2079.
5. Allen, H.A., F. Gongmin and B. Deng. 1993. Analysis of acid volatile sulfide (AVS) and simultaneously extracted metals (SEM) for estimation of potential toxicity in aquatic sediments. Environ. Toxicol. Chem. 12:1441-1453.
6. Tessier, A., P.G.C. Campbell and M. Bisson. 1979. Sequential extraction procedure for the speciation of paniculate trace metals. Anal. Chem. 51:844-851.
7. Berner, R.A. 1980. Early Diagenesis. A Theoretical Approach. Princeton University Press. Princeton, NJ, USA.
8. Boudreau, B.P. 1991. Modelling the sulfide-oxygen reaction and associated pH gradients in porewaters. Geochim. Cosmochim. Acta 55:145-159.
9. 3 dissolution at the deep-sea floor. Geochim. Cosmochim. Acta 58:2799-2809.
10. Boudreau, B.P. 1986. Mathematics of tracer mixing in sediments: I. Spatially-dependent diffusive mixing. Am. J. Sci. 286:161-198.
11. McCall, P.L. and M.J.S. Tevesz. 1982. The effects of benthos on physical properties of freshwater sediments. In P.L. McCall and M.J.S. Tevesz, eds., Animal-Sediment Relations. The Biogenie Alteration of Sediments. Plenum, New York, NY, USA, pp. 105-176.
12. Di Toro, D.M. and J.F. Fitzpatrick. 1993. Chesapeake Bay sediment flux model. Contract Report EL-93-2. U.S. Army Engineer Waterways Experiment Station, Vicksburg, MS.
13. Di Toro, D.M. 1997. Sediment Flux Modeling. John Wiley & Sons, New York, NY, USA.
14. Matisoff, G. 1982. Mathematical models of bioturbation. In P.L. McCall and M.J.S. Tevesz, eds., Animal-Sediment Relations. The Biogenic Alteration of Sediments. Plenum, New York, NY, USA, pp. 289-330.
15. Berner, R.A. 1980. A rate model for organic matter decomposition during bacterial sulfide reduction in marine sediments. In Biogeochemislry of Organic Matter at the Sediment-Water Interface. Comm. Natl. Recherche Scientific, France, pp. 35-44.
16. Westrich, J.T. and R.A. Berner. 1984. The role of sedimentary organic matter in bacterial sulfate reduction: The G model tested. Limnol. Oceanogr. 29:236-249.
17. Morse, J.W., F.J. Millero, J.C. Cornwell and D. Rickard. 1987 The chemistry of the hydrogen sulfide and iron sulfide systems in natural waters. Earth Sci. Rev. 24:1-42.
18. Dzombak, D.A. and F.M.M. Morel. 1990. Surface Complexation Modeling. Hydrous Ferric Oxide. John Wiley & Sons, New York, NY, USA.
19. Forssberg, K.S. 1985. Flotation of Sulphide Minerals. Elsevier, New York, NY, USA.
20. Nelson, M.B. 1978. Kinetics and Mechanisms of the Oxidation of Ferrous Sulfide. Ph.D. thesis. Stanford University, Palo Alto, CA, USA.
21. Di Toro, D.M., J.D. Mahony and A.M. Gonzalez. 1996. Particle oxidation model of synthetic iron sulfide and sediment acid-volatile sulfide. Environ. Toxicol. Chem. 15:2156-2167.
22. Carnahan, B., H.A. Luther and J.O. Wilkes. 1969. Applied Numerical Methods. John Wiley & Sons, New York, NY, USA.
23. Di Toro, D.M., J.J. Fitzpatrick and R.R. Isleib. 1994. A model of manganese and iron fluxes from sediments. Technical Report. HydroQual, Mahwah, NJ, USA.
24. Valiela, I. 1995. Marine Ecological Processes. Springer-Verlag, New York, NY, USA.
25. Hargrave, B.T. 1984. Sinking of particulate matter from the surface water of the ocean. In J.E. Hobbie and P.J. Leb, eds., Heterotrophic Activity in the Sea. Plenum, New York, NY, USA.
26. Mahony, J.D., D.M. Di Toro, A.M. Gonzalez, M. Curto, M. Dilg, L.D. De Rosa and L.A. Sparrow. 1996. Partitioning of metals to sediment organic carbon. Environ. Toxicol. Chem. 15: 2187-2197.
27. Carignan, R., F. Rapin and A. Tessier. 1985. Sediment porewater sampling for metal analysis: A comparison of techniques. Geochim. Cosmochim. Acta 49:2493-2497.
28. Hare, L., R. Carignan and M.A. Huerta-Diaz. 1994. A field study of metal toxicity and accumulation by benthic invertebrates; implication for the acid-volatile sulfide (AVS) model. Limnol. Oceanogr. 39:1653-1668.
29. Liber, K., D.J. Call, T.P. Markee, K.L. Schmude, M.D. Balcer, F.W. Whiteman and G.T. Ankley. 1996. Effects of acid-volatile sulfide on zinc bioavailability and toxicity to benthic macroinvertebrates: A spiked-sediment field experiments. Environ. Toxicol. Chem. 15:2113-2125.
30. DeWitt, T.H., R.C. Swartz, D.J. Hansen, D. McGovern and W.J. Berry. 1996. Bioavailability and chronic toxicity of cadmium in sediment to the estuarine amphipod Leptocheirus plumulosus. Environ. Toxicol. Chem. 15:2095-2101.
31. Sibley, P.K., G.T. Ankley, A.M. Cotter and E.N. Leonard. 1996. Predicting chronic toxicity of sediments spiked with zinc: An evaluation of the acid-volatile sulfide model using a life-cycle test with the midge Chironomus tentans. Environ. Toxicol. Chem. 15:2102-2112.
32. Peterson, G.S., G.T. Ankley and E.N. Leonard. 1996. Effect of bioturbation on metal-sultide oxidation in surficial freshwater sediments. Environ. Toxicol. Chem. 15:2147-2155.
33. Press, W.H., B.P. Flannery, S.A. Teukolsky and W.T. Vetterling. 1989. Numerical Recipes. The Art of Scientific Computing. (FORTRAN Version). Cambridge University Press, New York, NY, USA.
34. Krishnaswami, S. and D. Lal. 1978. Radionuclide limnochronology. In A. Lerman, ed., Lakes, Chemistry, Geology, Physics. Springer-Verlag, New York, NY, USA, pp. 153-177.
35. Tessier, A., Y. Couillard, P.G.C. Campbell and J.C. Auclair. 1993. Modeling Cd partitioning in oxic lake sediments and Cd concentrations in the freshwater bivalve: Anodonta grandis (Mollusca, Pelecypoda). Limnol. Oceanogr. 38:1-17.