Synthesis and characterization of tricarbonyl[η6-(phenylethynyl)arene]criromium complexes: Crystal structure of tricarbonyl[η6-(3-phenylethynyl) anisole]chromium

Journal of Organometallic Chemistry

Volumn 506, Issue 1-2, 1996, Pages 101-107

  Hong, Fung E ^a   Lo, Shih Chun ^a   Liou, Ming Woei ^a   Chang, Yuan Terng ^a   Lin, Chu Chieh ^a  

^a NATIONAL CHUNG HSING UNIVERSITY   (Taiwan)

Author keywords

Chromium; Nucleophilic substitution; Phenylethynylarene

Indexed keywords

ARENE;

EID: 0030529371     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(95)05596-H     Document Type: Article

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31. The reaction was performed by the procedure described in [3] except with a prolonged reaction time to 3.5 days. CTLC was used as the purification method.
32. No desired product could be obtained without adding HMPA in this reaction.
33. 35 = 1.1 Hz.
34. In addition, about 17% of starting material was recovered.