Concave reagents - Design and application

Journal of Inclusion Phenomena and Molecular Recognition in Chemistry

Volumn 24, Issue 1-2, 1996, Pages 43-60

  Lüning, Ulrich ^a  

^a UNIVERSITY OF KIEL   (Germany)

Author keywords

1,10 phenanthroline; Concave reagents; Macrocycle; Pyridine; Selectivity

Indexed keywords

EID: 0030527325     PISSN: 09230750     EISSN: None     Source Type: Journal    
DOI: 10.1007/bf01053425     Document Type: Review

References (26)

1. 1. Review: U. Lüning: Top. Curr. Chem. 1995, 175, 57.
2. 2. The term bimacrocycle will be used instead of macrobicycle because bimacrocycles often also contain smaller rings (e.g. aryl rings). They are thus macropolycyclic although only two macrocycles exist. (In addition, no bicycle company has offered sponsorship yet.)
3. 3. (a) Concave Reagents 1: U. Lüning: Liebigs Ann. Chem. 949 (1987).
4. (b) Concave Reagents 3: U. Lüning, R. Baumstark, K. Peters, and H. G. v. Schnering: Liebigs Ann. Chem. 129 (1990).
5. (c) Concave Reagents 8: U. Lüning, R. Baumstark, and M. Müller: Liebigs Ann. Chem. 987 (1991).
6. 4. (a) Concave Reagents 5: U. Lüning and M. Müller: Chem. Ber. 123, 643 (1990).
7. (b) Concave Reagents 15: U. Lüning, M. Müller, M. Gelbert, K. Peters, H. G. von Schnering, and M. Keller: Chem. Ber. 127, 2297 (1994).
8. 5. Concave Reagents 14: U. Lüning, R. Baumstark, and W. Schyja: Tetrahedron Lett. 34, 5063 (1993).
9. 6. (a) Concave Reagents 7: U. Lüning, C. Wangnick, K. Peters, and H. G. v. Schnering: Chem. Ber. 124, 397 (1991).
10. (b) Concave Reagents 11: U. Lüning and C. Wangnick: Liebigs Ann. Chem. 481 (1992).
11. 7. Concave Reagents 17: U. Lüning, H. Baumgartner and C. Wangnick: Tetrahedron 52, 599 (1996).
12. 8. QCPE program No. 429 by M. L. Connolly, used with Chem-X, developed and distributed by Chemical Design Ltd, Oxford, England.
13. 9. The term general and specific protonation is used in the same sense as the terms general and specific acid catalyses are used: specific means a specific protonated solvent molecule is the reacting species while general means that in general all acids in solution contribute to the reaction.
14. 10. U. Lüning, C. Wangnick, and M. Kümmerlin: Chem. Ber. 127, 2431 (1994).
15. 11. Review: H. W. Pinnick: Organic Reactions 38, 655 (1990).
16. 12. (a) Concave Reagents 4: U. Lüning, R. Baumstark, M. Müller, C. Wangnick, and F. Schillinger: Chem. Ber. 123, 221 (1990).
17. (b) Concave Reagents 6: U. Lüning and F. Schillinger: Chem. Ber. 123, 2073 (1990).
18. (c) Concave Reagents 10: U. Lüning and M. Müller: Angew. Chem. 104, 99 (1992); Int. Ed. Engl. 31, 80.
19. (c) Concave Reagents 10: U. Lüning and M. Müller: Angew. Chem. 104, 99 (1992); Int. Ed. Engl. 31, 80.
20. 13. W. Hacker: Dissertation, Universität Freiburg, in preparation.
21. 14. Concave Reagents 9: U. Lüning, R. Baumstark, and W. Schyja: Liebigs Ann. Chem. 999 (1991).
22. a scale. For the definition of log K see: Concave Reagents 2: U. Lüning and M. Müller: Liebigs Ann. Chem. 367 (1989).
23. 16. M. Gelbert: Dissertation, Universität Freiburg, 1995.
24. 17. Concave Reagents 16: H. Ross and U. Lüning, Angew. Chem., 107, 2723 (1995); Int. Ed. Engl. 34, 2555.
25. 17. Concave Reagents 16: H. Ross and U. Lüning, Angew. Chem., 107, 2723 (1995); Int. Ed. Engl. 34, 2555.
26. 18. Concave Reagents 12: U. Lüning and M. Gerst: J. Prakt. Chem./Chem.-Ztg. 334, 656 (1992).