Novel negatively charged cyanocuprate(I) host [Cu4(CN)7]3- built of tetrahedral Cu(I) coordination centers: Crystal structure of [{NH2(CH2CH2)2NCH2CH2NH2}2H][Cu4(CN)7]

Journal of Inclusion Phenomena and Molecular Recognition in Chemistry

Volumn 26, Issue 1-3, 1996, Pages 119-126

  Yuge, Hidetaka ^a   Iwamoto, Toschitake ^b  

^a KITASATO UNIVERSITY   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

Author keywords

Bifurcated cyano group; Crystal structure; Cyanocuprate(I) complex; Dimeric onium guest; Hydrogen bond; N (2 aminoethyl)piperazine; Three dimensional framework

Indexed keywords

EID: 0030525352     PISSN: 09230750     EISSN: None     Source Type: Journal    
DOI: 10.1007/BF01029936     Document Type: Article

References (28)

1. 1. T. Iwamoto: 'The Hofmann-type and Related Inclusion Compounds', Ch. 2 in J.L. Atwood, J.E.D. Davies, and D.D. MacNicol (eds.), Inclusion Compounds, Vol. 1, Academic Press, London (1984), p. 29; 'Inclusion Compounds of Multi-dimensional Cyanometal Complex Hosts', Ch. 6 in J.L. Atwood, J.E.D. Davies, and D.D. MacNicol (eds.), Inclusion Compounds, Vol. 5, Oxford University Press, Oxford (1991), p. 172.
2. 1. T. Iwamoto: 'The Hofmann-type and Related Inclusion Compounds', Ch. 2 in J.L. Atwood, J.E.D. Davies, and D.D. MacNicol (eds.), Inclusion Compounds, Vol. 1, Academic Press, London (1984), p. 29; 'Inclusion Compounds of Multi-dimensional Cyanometal Complex Hosts', Ch. 6 in J.L. Atwood, J.E.D. Davies, and D.D. MacNicol (eds.), Inclusion Compounds, Vol. 5, Oxford University Press, Oxford (1991), p. 172.
3. 2. H. Yuge and T. Iwamoto: J. Chem. Soc., Dalton Trans. 1237 (1994); idem. Acta Crystallogr., Sect. C, 51, 374 (1995).
4. 2. H. Yuge and T. Iwamoto: J. Chem. Soc., Dalton Trans. 1237 (1994); idem. Acta Crystallogr., Sect. C, 51, 374 (1995).
5. 3. T. Kitazawa, S. Nishikiori, R. Kuroda, and T. Iwamoto: J. Chem. Soc., Dalton Trans. 1029 (1994); T. Kitazawa, S. Nishikiori, and T. Iwamoto: ibid. 3695 (1994).
6. 3. T. Kitazawa, S. Nishikiori, R. Kuroda, and T. Iwamoto: J. Chem. Soc., Dalton Trans. 1029 (1994); T. Kitazawa, S. Nishikiori, and T. Iwamoto: ibid. 3695 (1994).
7. 4. H. Yuge and T. Iwamoto: J. Incl. Phenom. 14, 217 (1992); idem: J. Chem. Soc., Dalton Trans. 2841 (1993).
8. 4. H. Yuge and T. Iwamoto: J. Incl. Phenom. 14, 217 (1992); idem: J. Chem. Soc., Dalton Trans. 2841 (1993).
9. 5. S. Nishikiori and T. Iwamoto: J. Chem. Soc., Chem. Commun. 1555 (1993); S. Nishikiori and T. Iwamoto: Chem. Lett. 1199 (1994).
10. 5. S. Nishikiori and T. Iwamoto: J. Chem. Soc., Chem. Commun. 1555 (1993); S. Nishikiori and T. Iwamoto: Chem. Lett. 1199 (1994).
11. 6. T. Soma and T. Iwamoto: Chem. Lett. 821 (1994); T. Soma, H. Yuge, and T. Iwamoto: Angew. Chem., Int. Ed. Engl. 33 1665 (1994); T. Soma and T. Iwamoto: Chem. Lett. 271 (1995).
12. 6. T. Soma and T. Iwamoto: Chem. Lett. 821 (1994); T. Soma, H. Yuge, and T. Iwamoto: Angew. Chem., Int. Ed. Engl. 33 1665 (1994); T. Soma and T. Iwamoto: Chem. Lett. 271 (1995).
13. 6. T. Soma and T. Iwamoto: Chem. Lett. 821 (1994); T. Soma, H. Yuge, and T. Iwamoto: Angew. Chem., Int. Ed. Engl. 33 1665 (1994); T. Soma and T. Iwamoto: Chem. Lett. 271 (1995).
14. 7. C. Kappenstein and R.P. Hugel: Inorg. Chem. 17, 1945 (1978).
15. 8. R.B. Roof, Jr., A.C. Larson, and D.T. Cromer: Acta Crystallogr., Sect. B, 24, 269 (1968).
16. 9. D.T. Cromer: J. Phys. Chem. 61, 1388 (1957); C. Kappenstein and R.P. Hugel: Inorg. Chem. 16, 250 (1977).
17. 9. D.T. Cromer: J. Phys. Chem. 61, 1388 (1957); C. Kappenstein and R.P. Hugel: Inorg. Chem. 16, 250 (1977).
18. 10. D.T. Cromer and A.C. Larson: Acta Crystallogr. 15, 397 (1962).
19. 11. R.J. Williams, A.C. Larson, and D.T. Cromer: Acta Crystallogr., Sect. B, 28, 858 (1972).
20. 12. M. Asplund, S. Jagner, and M. Nilsson: Acta Chem. Scand. A37, 165 (1983).
21. 13. U. Geiser, H.H. Wang, K.D. Carlson, J.M. Williams, H.A. Charlier, Jr., J.E. Heindl, G.A. Yaconi, B.J. Love, M.W. Lathrop, J.E. Schirber, D.L. Overmyer, J. Ren, and M.-H. Whangbo: Inorg. Chem., 30, 2586 (1991).
22. 14. J. Černák, K. Györyová, Š. Sabolová, and M. Dunaj-Jurčo: Inorg. Chim. Acta 185, 119 (1991).
23. 15. M.B. Inoue, M. Inoue, L. Machi, F. Brown, and Q. Fernando: Inorg. Chim. Acta 230, 145 (1995).
24. 16. G.M. Sheldrick: Acta Crystallogr., Sect. A, 46, 467 (1990).
25. 17. G.M. Sheldrick: SHELXL93 Program for the Refinement of Crystal Structures. Univ. of Göttingen, Germany, 1993.
26. 18. D.T. Cromer, A.C. Larson, and R.B. Roof, Jr.: Acta Crystallogr. 19, 192 (1965).
27. 19. International Tables for Crystallography, Vol. C, pp. 500, Kluwer Academic Publishers, Dordrecht, 1995.
28. 20. C.K. Johnson: ORTEPII Report ORNL-5138, Oak Ridge National Laboratory, Tennessee, U.S.A., 1976.