Direct observation of hydrogen-deuterium exchange reaction in cobaloxime crystal by neutron diffraction

Chemistry Letters

Volumn , Issue 6, 1996, Pages 445-446

  Ohgo, Yoshiki ^a   Ohashi, Yuji ^a   Klooster, Wim T ^b   Koetzle, Thomas F ^b  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b BROOKHAVEN NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0030501626     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1996.445     Document Type: Article

References (12)

1. Y. Ohashi, Acc. Chem. Res., 21, 268 (1988).
2. Y. Ohashi, K. Yanagi, T. Kurihara, Y. Sasada, and Y. Ohgo, J. Am.Chem.Soc., 103, 5805 (1981).
3. Y. Sakai, H. Sato, Y. Ohashi, Y. Arai, and Y. Ohgo, Analytical Sciences, 11, 873 (1995).
4. G. Moad, D. H. Solomon, and R. I. Willing, Macromolecules, 21, 857 (1988).
5. Y. Ohgo, S. Takeuchi, Y. Natori, J. Yoshimura, Y. Ohashi, and Y. Sasada, Bull. Chem. Soc. Jpn., 54, 3095 (1981).
6. 58923 +58.5°(c 0.11, chloroform). The NMR measurement of the chlorofolm solution of the compound before irradiation showed that the deuterium atom was substituted completely and only to the H9 position.
7. o) and S = 1.15 for all data.
8. G. M. Sheldrick, SHELXL-93, Program for the Refinement of CrystalStructures. University of Goettingen, Germany (1993).
9. Y. Ohashi, Y. Sasada, S. Takeuchi, and Y. Ohgo, Bull. Chem. Soc. Jpn., 53, 627 (1980).
10. C. K. Johnson, ORTEPII, Report ORNL-5138. Oak Ridge NationalLaboratory, Tennessee (1976).
11. The authors have deposited atomic coordinates at the CambridgeCrystallographic Data Center. The coordinates can be obtained on the request from The Director, Cambridge Crystallographic Data Center, 12 Union Road, Cambridge CB2 1EZ, UK.
12. L. Koester, Springer Tracts in Modern Physics. Vol. 80, Neutron Physics(1977).