Synthesis and structural determination of 1,1′-spirobi(3H-2,1-benzoxatellurole)-3-one ([10-Te-4(C2O2)]): Conversion of diacyloxyspirotellurane to alkoxyspirotellurane by reduction with lithium aluminium hydride

Chemistry Letters

Volumn , Issue 5, 1996, Pages 365-366

  Takaguchi, Yutaka ^a   Furukawa, Naomichi ^a  

^a UNIVERSITY OF TSUKUBA   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0030488577     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1996.365     Document Type: Article

References (23)

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13. A. Kálmán, K. Sasvari, and I. Kapovits, Acta Cryst., B29, 355 (1973); I. Kapovits, J. Rábai, D. Szabó, K. Czakó, A. Kucsman, G. Argay, V. Fülöp, A. Kálmán, T. Koritsánszky, and L. Párkányi, J. Chem. Soc., Perkin Trans. 2, 847 (1993); J. Rábai, I. Kapovits, G. Argay, T. Koritsánszky, and A. Kálman, J. Chem. Soc., Chem. Commun., 1069 (1995); B. Dahlen and B. Lindgrew, Acta Chem. Scand., 27, 2218 (1973); H. J. Reich, J. Am. Chem. Soc., 95, 964 (1973); J. C. Martin and R. J. Arhart, J. Am. Chem. Soc., 86, 2339 (1971).
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17. General procedures were shown in the following: a solution of 1,1′-spirobi(3H-2,1-benzoxatellurole)-3,3′-dione (1) (200 mg, 0.544 mmol) in dry THF (80 ml) was added dropwise to a suspension of lithium aluminium hydride (103 mg, 2.72 mmol) in dry THF (100 ml) at 0°C. The whole mixture was stirred at room temperature for 18 h. After usual work-up the residue was purified by silica-gel column chromatography (methanol/chloroform 1:10) and HPLC to give the colorless crystal 2 (45 mg, 0.125 mmol, yield 23%), 3 (28 mg, 0.082 mmol, yield 15%) and 4 (45 mg, 0.413 mmol, yield 38%).
18. + - 28, 32.8%).
19. I. D. Sadekov, A. A. Maksimenko, and V. I. Minkin, Khimiya Geterotsiklicheslch Soedineni, 103, 2715 (1981).
20. w = 0.024, 2199 measured reflections, 2029 unique, 1999 observed (I > 3.0σ(I)). Hydrogen atoms were placed in calculated positions.
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