High-temperature Raman spectroscopic and X-ray diffraction study of β-Mg2SiO4: Insights into its high-temperature thermodynamic properties and the β- to α-phase-transformation mechanism and kinetics

American Mineralogist

Volumn 81, Issue 5-6, 1996, Pages 585-594

  Reynard, Bruno ^a   Takir, Fouzia ^a   Guyot, François ^b,d   Gwanmesia, Gabriel D ^b   Liebermann, Robert C ^b   Gillet, Philippe ^c  

^a UNIVERSITÉ DE RENNES 1   (France)

^b STONY BROOK UNIVERSITY   (United States)

^c UNIVERSITÉ DE LYON   (France)

^d UNIVERSITÉ PIERRE ET MARIE CURIE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; KINETICS; MARTENSITIC TRANSFORMATIONS; METADATA; OLIVINE; ORGANIC POLYMERS; RAMAN SCATTERING; RAMAN SPECTROSCOPY; SILICON; SPECIFIC HEAT; X RAY DIFFRACTION; X RAY POWDER DIFFRACTION;

EQUILIBRIUM CONDITIONS; HIGH TEMPERATURE RAMAN SPECTRA; IN-SITU RAMAN SPECTROSCOPY; MECHANISM AND KINETICS; MODERATE TEMPERATURE; RAMAN FREQUENCY SHIFTS; TRANSFORMED FRACTION; X-RAY DIFFRACTION STUDIES;

TEMPERATURE;

OLIVINE; PHASE TRANSITION; RAMAN SPECTROSCOPY; REACTION KINETICS; THERMODYNAMICS; XRD;

EID: 0030479406     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am-1996-5-605     Document Type: Article

References (45)

1. 4: Calorimetric measurements, thermochemical calculation, and geophysical application. Journal of Geophysical Research, 94, 15671-15685.
2. Avrami, M. (1939) Kinetics of phase change: I. General theory. Journal of Chemical Physics, 7, 1103-1112.
3. _ (1940) Kinetics of phase change: II. Transformation-time theory for random distribution of nuclei. Journal of Chemical Physics, 8, 212-224.
4. _ (1941) Kinetics of phase change: III. Granulations, phase change, and microstructure. Journal of Chemical Physics, 9, 177-184.
5. 4. Geophysical Research Letters, 10, 87-90.
6. 4 via faulted structures. Nature, 303, 233-235.
7. 4 at 15 GPa. Physics and Chemistry of Minerals, 18, 343-358.
8. Burnley, P.C., and Green, H.W. (1989) Stress dependence of the olivine-spinel transformation. Nature, 338, 753-756.
9. Cahn, J.W. (1956) The kinetics of grain boundary nucleated reactions. Acta Metallica, 4, 449-459.
10. Carlson, W.D., and Rosenfeld, J.L. (1981) Optical determination of topotactic aragonite-calcite growth kinetics: Metamorphic implications. Journal of Geology, 89, 615.
11. 4 (modified spinel) at mantle pressures derived from vibrational spectroscopy: Implications for the mantle at 400 km. Journal of Geophysical Research, 96, 11817-11830.
12. 2 laser heated diamond anvil cell: Perovskite and clinopyroxene. In Geophys Monograph, 67, 101-108.
13. 4) crystal and glass. American Mineralogist, 78, 1143-1148.
14. 4. Physics and Chemistry of Minerals, 18, 469-479.
15. 4: Some insights on anharmonicity. Physics of the Earth and Planetary Interiors, 58, 141-154.
16. Gillet, P., Richet, P., Guyot, P., and Fiquet, G. (1991) High-temperature thermodynamic properties of forsterite. Journal of Geophysical Research, 96, 11805-11816.
17. 4. Geophysical Research Letters, 18, 89-92.
18. 4 for acoustic velocity measurements. Geophysical Research Letters, 17, 1331-1334.
19. Hyde, B.G., White, T.J., O'Keeffe, M., and Johnson, A.W.S. (1982) Structures related to those of spinel and the β-phase, and a possible mechanism for the transformation olivine-spinel. Zeitschrift für Kristallographie, 160, 53-62.
20. 4 at high pressures and temperatures: Precise determinations of stabilities of olivine, modified spinel and spinel. Journal of Geophysical Research, 94, 15663-15670.
21. Lacam, A., Madon, M., and Poirier, J.P. (1980) Olivine glass and spinel formed in laser heated, diamond anvil high-pressure cell. Nature, 228, 155-157.
22. 4 in shocked meteorites: Planar defects and polymorphic transitions. Physics of the Earth and Planetary Interiors, 33, 31-44.
23. Madon, M., and Gillet, P. (1984) A theoretical approach to the kinetics of calcite ↔ aragonite transition: Application to laboratory experiments. Earth and Planetary Science Letters, 67, 400-414.
24. Madon, M., Guyot, F., Peyronneau, J., and Poirier, J.P. (1989) Electron microscopy of high-pressure phases synthesized from natural olivine in diamond anvil cell. Physics and Chemistry of Minerals, 16, 320-330.
25. Mammone, J.F., and Sharma, S.K. (1979) Pressure and temperature dependence of the Raman spectra of rutile-structure oxides. Carnegie Institution of Washington Year Book, 78, 369-373.
26. 4 (spinel). American Mineralogist, 72, 361-364.
27. 4. American Mineralogist, 76, 354-360.
28. Poirier, J.P. (1981a) Martensitic olivine spinel transformation and plasticity of the mantle transition zone. In Anelasticity in the Earth, 4, 113-117.
29. _ (1981b) On the kinetics of olivine-spinel transition. Physics of the Earth and Planetary Interiors, 26, 179-185.
30. 4 from the Peace River meteorite. Physics of the Earth and Planetary Interiors, 33, 137-147.
31. 4 from the Peace River meteorite. Canadian Mineralogist, 21, 29-35.
32. 4. Physics and Chemistry of Minerals, 15, 498-506.
33. 4. European Journal of Mineralogy, 5, 31-35.
34. 4-olivine: A Raman spectroscopic study. Physics and Chemistry of Minerals, 20, 556-562.
35. Rubie, D.C., and Thompson, A.B. (1985) Kinetics of metamorphic reactions at elevated temperatures and pressures: An appraisal of experimental data. In Advances in Physical Geochemistry, 4, 291 p.
36. 4 olivine to spinel. Bulletin de Minéralogie, 110, 471-480.
37. 4 olivine-spinel transformation. Journal of Geophysical Research, 95, 15829-15844.
38. 4. Journal of Physics of the Earth, 28, 273-280.
39. 4. Eos, 69, 498.
40. Vaughan, P.J., Green, H.W., and Coe, R.S. (1982) Is the olivine-spinel phase transformation martensitic? Nature, 298, 357-358.
41. 4 under nonhydrostatic stress. Tectonophysics, 108, 299-322.
42. Watanabe, H. (1982) Thermochemical properties of synthetic high-pressure compounds relevant to the Earth's mantle. In S. Akimoto and M.H. Manghnani, Eds., High-pressure research in geophysics, p. 441-464. Center for Academic Publications, Tokyo.
43. 4. In M.H. Manghnani and Y. Syono, Eds., High pressure in mineral physics, p. 177-186. AGU, Washington, DC.
44. 4 as a function of temperature and heating duration. Physics and Chemistry of Minerals, 13, 227-232.
45. 4 spinel at elevated temperature. Physics and Chemistry of Minerals, 13, 156-160.