[Rh(7-SPh-8-Me-7,8-C2B9H10)(PPh 3)2]: A new rhodacarborane with enhanced activity in the hydrogenation of 1-alkenes

Angewandte Chemie (International Edition in English)

Volumn 35, Issue 19, 1996, Pages 2251-2253

  Teixidor, Francesc ^a   Flores, Miquel A ^a   Viñas, Clara ^a   Kivekäs, Raikko ^b   Sillanpää, Reijo ^c  

^a UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

^b UNIVERSITY OF HELSINKI   (Finland)

^c UNIVERSITY OF TURKU   (Finland)

Author keywords

Boron compounds; Catalysis; Hydrog nations; Rhodium compounds

Indexed keywords

EID: 0030472829     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199622511     Document Type: Article

References (13)

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2. Examples: a) H. C. Kang, M. F. Hawthorne, Organometallics 1990, 9, 2327-2332.
3. Other catalytic applications of metallacarboranes: b) A. Demonceau, E. Saive, Y. de Froidmont, A. F. Noels, A. J. Hubert, Tetrahedron Lett. 1992, 33, 2009-2012; c) B. Pirotte, A. Felekidis, M. Fontaine, A. Demonceau, A. F. Noels, J. Delarge, ibid 1993, 34, 1471-1474.
4. Other catalytic applications of metallacarboranes: b) A. Demonceau, E. Saive, Y. de Froidmont, A. F. Noels, A. J. Hubert, Tetrahedron Lett. 1992, 33, 2009-2012; c) B. Pirotte, A. Felekidis, M. Fontaine, A. Demonceau, A. F. Noels, J. Delarge, ibid 1993, 34, 1471-1474.
5. J. A. Belmont, J. Soto, R. E. King, A. J. Donaldson, J. D. Hewes, M. F. Hawthorne, J. Am. Chem. Soc. 1989, 111, 7475-7486, and references therein.
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7. b) F. Teixidor, C. Viñas, J. Casabó, A. M. Romerosa, J. Rius, C. Miravitlles, Organometallics 1994, 13, 914-919.
8. R. T. Baker, M. S. Delaney, R. E. King, C. B. Knobler, J A. Long, T. B. Marder, T. E. Paxson, R. G. Teller, M. F. Hawthorne, J. Am. Chem. Soc. 1984, 106, 2965-2978.
9. J. A. Long, T. B. Marder, P. E. Behnken, M. F. Hawthorne, J. Am. Chem. Soc. 1984, 106, 2979-2989.
10. -3. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-179-77. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: int. code + (1223) 336-033; e-mail: teched@chemcrys.cam.ac.uk).
11. Yields represent averaged values for three runs.
12. This is the TON that we can obtain with the volume of our reactor. However, the real maximum number seems to far exceed this figure.
13. R. R. Schrock, J. A. Osborn, J. Am. Chem. Soc. 1976, 98, 2134-2142.