Crystal structures and properties of cyclic polyenes possessing disulfide units

Angewandte Chemie (International Edition in English)

Volumn 35, Issue 20, 1996, Pages 2357-2359

  Shimizu, Toshio ^a   Iwata, Kazuko ^a   Kamigata, Nobumasa ^a  

^a TOKYO METROPOLITAN UNIVERSITY   (Japan)

Author keywords

Cyclizations; Polyenes; Sulfur compounds; Synthetic methods

Indexed keywords

EID: 0030472294     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199623571     Document Type: Article

References (24)

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10. K. B. Borisenko, M. Broschag, I. Hargittai, T. M. Klapötke, D. Schröder, A. Schulz, H. Schwarz, I. C. Tornieporth-Oetting, P. S. White, J. Chem. Soc., Dalton Trans. 1994, 2705.
11. 3.
12. -1, Z = 4, orthorhombic, space group Pbcn (No. 60), Mac Science MXC 18 diffractometer, λ = 0.71069 Å, T = 296 K, 1528 measured reflections, 1262 independent, R = 0.042, Rw = 0.055. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-179-95. Copies of the data can be obtained free of charge on application to the Director, CCDC, 12 Union Rd, GB-Cambridge CB21EZ, UK (fax: int. code +(1223)336-033; e-mail: teched@chemcrys.cam.ac.uk).
13. 1/c (No. 14), Mac Science MXC 18 diffractometer, λ = 0.71069 Å, T = 296 K, 3843 measured reflections, 3368 independent, R = 0.043, Rw = 0.041.
14. Among the three geometries (twist, chair, and half-chair) optimized for 1 at the local minima, the twist form was calculated to lie on the lowest potential level (MP2/D95*).
15. T. Shimizu, K. Iwata, N. Kamigata, S. Ikuta, J. Chem. Res. (S) 1994, 436.
16. Ab initio MO calculations (MP2/D95*) on dimethyl disulfide provided a dihedral angle of 89.1° at the global minimum.
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18. A. Veillard, J. Demuynck, Chem. Phys. Lett. 1970, 4, 476; A. Rauk, J. Am. Chem. Soc. 1984, 106, 6517; R. Block, L. Jansen, J. Chem. Phys. 1985, 82, 3322; D. A. Dixon, D. Zeroka, J. J. Wendoloski, Z. R. Wasserman, J. Phys. Chem. 1985, 89, 5334.
19. A. Veillard, J. Demuynck, Chem. Phys. Lett. 1970, 4, 476; A. Rauk, J. Am. Chem. Soc. 1984, 106, 6517; R. Block, L. Jansen, J. Chem. Phys. 1985, 82, 3322; D. A. Dixon, D. Zeroka, J. J. Wendoloski, Z. R. Wasserman, J. Phys. Chem. 1985, 89, 5334.
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21. Combustion analysis for CHS (calcd, found): C 26.64, 27.54; H 2.24, 2.23.
22. 4 (calcd, found): C 45.76, 46.07; H 5.38, 5.31.
23. W. Schroth, J. Peschel, Chimia 1964, 18, 171.
24. H. E. Wijers, H. Boelens, A. van der Gen, L. Brandsma, Red. Trav. Chim., Pays-Bas 1969, 88, 519.