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Some compounds such as HCFC-22, and HCFC-142b undergo slower decomposition in the stratosphere than do most CFCs and are only partially decomposed, even in the most photochemically aged air reaching the lower polar stratosphere (22).
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85069132937
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3 in the stratosphere is well estimated by the amount of halocarbon that has been destroyed in the stratosphere. All computations involving the lower, mid-latitude stratosphere were made with alpha = 100 (3, 24, 26). In the calculation of ECI in the springtime polar vortex, we estimated alpha at 40 (2, 3, 13, 23-26).
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55
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3Br abundance; the maximum EECl or ECl would have occurred <0.5 year later. As an estimate for global tropospheric burden we use 10 ppt [J. M. Lobert et al., Science 267, 1002 (1995)].
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3Br abundance; the maximum EECl or ECl would have occurred <0.5 year later. As an estimate for global tropospheric burden we use 10 ppt [J. M. Lobert et al., Science 267, 1002 (1995)].
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note
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We are indebted to all personnel involved in collecting flask samples at the NOAA/CMDL Observatories and at cooperative sampling sites: P. J. Fraser and staff at the Cape Grim Baseline Air Pollution Station; M. Losleben (University of Colorado); and N. Trivett and staff at Alert Canada (Atmospheric Environment Service). We appreciate useful discussions with J. S. Daniel and the technical assistance of N. J. Condon. This work was supported in part by the Atmospheric Chemistry and Radiatively Important Trace Species components of NOAA's Climate and Global Change Program.
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