Reactions and reactivity of acyloxycarbenes

Journal of the American Chemical Society

Volumn 118, Issue 50, 1996, Pages 12588-12597

  Moss, Robert A ^a   Xue, Song ^a   Liu, Weiguo ^a   Krogh Jespersen, Karsten ^a  

^a RUTGERS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOPROPANE DERIVATIVE; DIKETONE; KETONE;

ARTICLE; DRUG SYNTHESIS; MOLECULAR DYNAMICS; PHOTOCHEMISTRY; REACTION ANALYSIS;

EID: 0030453602     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9626244     Document Type: Article

References (73)

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53. Structures 28a-c and 28aTS-cTS were reoptimized with electron correlation included at the MP2/6-31G* level. The MP2/6-31G*//6-31G*-optimized structures are not dramatically different from those obtained at the HF/6-31G*//6-31G* level, in particular conformer 28a-Z does persist as minimum at this computational level.
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56. a = 7.4 kcal/mol.
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66. 50
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